환경위생공학 (Journal of environmental and Sanitary engineering)
- 제13권1호
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- Pages.69-81
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- 1998
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- 2005-5889(pISSN)
환경오염을 줄이면서 고에너지원으로 이용되는 물질에 관한 연구
A Study on the Matter of Using High Energetic Source with Environmental Pollution Reduce
초록
The reactivity increase of unsunstituted energetic compound in cyclic ethers was found in order of three-membered cyclic form < five-membered cyclic form< four-membered cyclic form. The nucleophilicity and basicity of cyclic ethers can be explained by the negative charge on oxygen atom of cyclic ethers. The reactivity of propagation in the polymerization of cyclic ethers can be represented by positive charge on carbon atom and the LUMO energy of active species of cyclic ethers. The cationic polymerization of substituted cyclic ethers which have pendant energetic groups such as methoxy(
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