Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Dehydropolymerization of Silanes to Polysilanes Catalyzed by Organometallic Complexes

유기금속 착물 촉매에 의한 실란의 탈수소중합 반응

  • Woo, Hee Gweon (Department of Chemistry, College of Natural Science, Chonnam National University) ;
  • Song, Sun Jung (Department of Chemistry, College of Natural Science, Chonnam National University)
  • 우희권 (전남대학교 자연과학대학 화학과) ;
  • 송선정 (전남대학교 자연과학대학 화학과)
  • Published : 19970900
Download PDF
⟨ Previous Next ⟩

Abstract

This review deals with (1) the catalytic systems and mechanisms for the dehydropolymerization of silanes to polysilanes, (2) the dehydropolymerization of versatile silanes, (3) the preparation of polysilane derivatives, and (4) the applications of catalytic dehydropolymerizing systems to ceramics. The efforts to maximize the catalytic efficiency of group 4 metallocenes were introduced. Finally, the future of this dehydropolymerizing techniques of silanes was foreseen.

실란탈수소중합 반응을 위한 촉매들 및 중합반응 메카니즘들을 정리하여 기술하였다. 치환기 재분배 및 실란 소중합체를 생성하는 후기 전이금속 착물 촉매들과는 달리 전기 전이금속 착물 촉매들 특히 4족 전이금속 메탈로센계 촉매의 효과가 우수하였다. 4족 전이금속 메탈로센계 촉매의 효과를 극대화 하기위한 노력들을 소개하였으며, 또한 다양한 치환기를 갖는 실란고분자의 합성, 실란고분자 유도체의 합성, 탈수소중합 촉매의 세라믹 화학에의 응용예들을 기술 하였다. 마지막으로 실란의 탈수소중합법의 미래 전망을 살펴 보았다.

Keywords

References

  1. ACS Symposium Series 572 Inorganic and Organometallic Polymers II Wisian-Neilson, P.(ed.);Allcock, H. R.(ed.);Wynne, K. J.(ed.)
  2. Inoragnic Polymers Mark, J. E.;Allcock, H. R.;West, R.
  3. Silicon-containing Polymers Jones, R. G.(ed.)
  4. Chem. Lett. Yajima, S.;Omori, M.;Hayashi, J.;Okamura, K.;Matsuzawa, T.;Liwa, C. F.
  5. J. Am. Chem. Soc. v.110 Bianconi, P. A.;Weidman, T. W.
  6. Polym. Eng. Sci. v.23 Griffing, B. F.;West, R.
  7. J. Am. Chem. Soc. v.103 West, R.;David, L. D.;Djurovich, P. I.;Stearley, K. S. V.;Srinivasan, H. Y.
  8. J. Chem. Rev. v.89 Miller, R. D.;Michl, J.
  9. J. Organomet. Chem. v.300 West, R.
  10. Organometallics v.4 Trefonas, P.;Damewood, J. R.;West, R.;Miller, R. D.
  11. Macromolecules v.20 Harrah, L. A.;Zeigler, J. M.
  12. Macromolecules v.25 Fujino, M.;Hisaki, T.;Jujiki, M.;Matsumoto, N.
  13. Macromolecules v.23 Sakamoto, K.;Yoshida, M.;Sakurai, H.
  14. J. Macromol. Sci.-Chem. v.A28 Matyjaszewski, K.;Cypryk, m.;Frey, H.;Hrkach, J.;Kim, H. K.;Moeller, M.;Ruehl, K.;White, M.
  15. Angew. Chem. Int. Ed. Engl. v.15 Hengge, E.;Litscher, G. K.
  16. Macromolecules v.28 Matyjaszewski, K.;Greszta, D.;Hrkach, J. S.;Kim, H. K.
  17. Organometallics v.14 Kimata, Y.;Suzuki, H.;Satoh, S.;Kuriyama, A.
  18. J. Chem. Soc., Chem. Commun. Boudjouk, P.;Rajkumar, A. B.;Parker, W. L.
  19. Polym. Prepr.(Am. Chem. Soc., Div. Polym. Chem.) v.28 no.1 Becker, B.;Corriu, R.;Guerin, C.;Henner, B.
  20. Can. J. Chem. v.65 Aitken, C.;Harrod, J. F.;Gill, U. S.
  21. Organometallics v.6 Harrod, J. F.;Yun, S. S.
  22. Organometallics v.8 Aitken, C.;Barry, J.-P.;Gauvin, F.;Harrod, J. F.;Malek, A.;Rousseau, D.
  23. J. Am. Chem. Soc. v.111 Woo, H.-G.;Tilley, T. D.
  24. J. Am. Chem. Soc. v.111 Woo, H.-G.;Tilley, T. D.
  25. J. Am. Chem. Soc. v.114 Woo, H.-C.;Heyn, R. H.;Tilley, T. D.
  26. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.31 no.2 Woo, H.-G.;Tilley, T. D.
  27. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.32 no.1 Walzer, J. F.;Woo, H.-G.;Tilley, T. D.
  28. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.33 no.1 Tilley, T. D.;Radu, N. S.;Walzer, J. F.;Woo, H.-G.
  29. Adv. Organomet. Chem. v.6 Kumada, M.;Tamao, K.
  30. Adv. Organomet. Chem. v.19 Ishikawa, M.;Kumada, M.
  31. Adv. Organomet. Chem. v.19 Curtis, M. D.;Epstein, P. S.
  32. Comments Inorg. Chem. v.10 Tilley, T. D.
  33. Acc. Chem. Res. v.26 Tilley, T. D.
  34. Adv. Silicon Chem. v.1 Corey, J. Y.
  35. Ph. D. Thesis, University of California at San Diego Woo, H.-G.
  36. Organometallics v.12 Li, H.;Gauvin, F.;Harrod, J. F.
  37. Chem. Lett. Nakano, T.;Nakamura, H.;Nagai, Y.
  38. Organometallics v.14 Bourg, S.;Corriu, R. J. P.;Enders, M.;Moreau, J. J. E.
  39. Organometallics v.16 Jutzi, P.;Redeker, T.
  40. Organometallics v.15 Jutzi, P.;Redeker, T.;Neumann, B.;Stammler, H.-G.
  41. Choi, N.;Onozawa, S.-Y.;Sakakura, T.;Tanaka, M.
  42. Chem. Lett. Sakakura, T.;Lautenschlager, H.-J.;Nakajima, M.;Tanakam, M.
  43. Organometallics v.10 Forsyth, C. M.;Nolan, S. P.;Marks, T. J.
  44. U. S. Patent 4,965,386 Watson, P. L.;Tebbe, F. N.
  45. Chem. Abstr. v.114 Watson, P. L.;Tebbe, F. N.
  46. Bull. Korean Chem. Soc. v.17 Woo, H.-G.;song, S.-J.
  47. Manuscript in preparation Woo, H.-G.;Song, S.-J.
  48. Organometallics v.10 Corey, J. Y.;Zhu, X.-H.;Bedard, T. C.;Lange, L. D.
  49. Organometallics v.11 Corey, J. Y.;Zhu, X.-H.
  50. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.33 no.1 Corey, J. Y.;Joslin, F. L.;Braddock-Wilking, J.;Thompson, L. S.
  51. Organometallics v.12 Corey, J. Y.;Huhmann, J. L.;Zhu, X.-H.
  52. Organometallics v.11 Kesti, M. R.;Waymouth, R. M.
  53. Organometallics v.13 Knight, K. S.;Waymouth, R. M.
  54. J. Am. Chem. Soc. v.109 Buchwald, S. L.;Watson, B. T.;Huffman, J. C.
  55. Chem. Ber. v.122 Binger, P.;Muller, P.;Benn, R.;Rufinske, A.;Gabor, B.;Kruger, C.;Blitz, P.
  56. J. Am. Chem. Soc. v.111 Negishi, E.;Holmes, S. J.;Tour, J. M.;Miller, J. A.;Cederbaum, F. E.;Swanson, D. R.;Takahashi, T.
  57. J. Am. Chem. Soc. v.119 Soleil, F.;Choukroun, R.
  58. Organometallics v.16 Dioumaev, V. K.;Harrod, J. F.
  59. Organometallics v.14 Woo, H.-G.;Kim, S.-Y.;Han, M.-K.;Cho, E. J.;Jung, I. N.
  60. Bull, Korean Chem. Soc. v.16 Woo, H.-G.;Kim, S.-Y.;Kim, W.-G.;Yeon, S. H.;Cho, E. J.;Jung, I. N.
  61. Bull. Korean Chem. Soc. v.17 Woo, H.-G.;Song, S.-J.;You, H.;Cho, E. J.;Jung, I. N.
  62. Bull. Korean. Chem. Soc. v.17 Woo, H.-G.;Song, S.-J.
  63. German Patent 2,301,784 Kralicek, J.;Kubanek, V.;Kondelikova, J.
  64. German Patent 2,445,647 Kralicek, J.;Kbuanek, V.;Kondelikova, J.;Casensky, B.;Machacek, J.
  65. U.S. Patent 3,962,239 Bukac, Z.;Sebenda, J.
  66. Unpublished results Woo, H.-G.;Harrod, J. F.
  67. Organometallics v.11 Erker, G.
  68. Organometallics v.10 Horton, A. D.
  69. Organometallics v.10 Marks, T. J.
  70. Organometallics v.13 Dioumaev, V. K.;Harrod, J. F.
  71. Organomet. Chem. v.521 Dioumaev, V. K.;Harrod, J. F. J.
  72. Polyhedron v.13 Imori, T.;Tilleym, T. D.
  73. J. Am. Chem. Soc. v.113 Yang, X.;Stern, C. L.;Marks, T. J.
  74. J. Am. Chem. Soc. v.113 Chien, J. C. W.;Tsai, W.-M.;Rausch, M. D.
  75. J. Am. Chem. Soc. v.119 Xin, S.;Woo, H.-G.;Harrod, J. F.;Samuel, E.;Lebuis, A.-M.
  76. J. Am. Chem. Soc. Xin, S.;Woo, H.-G.;Harrod, J. F.;Ronghua, S.;Samuel, E.;Lebuis, A.-M.
  77. J. Organomet. Chem. v.55 Ojima, I.;Inaba, S.-I.;Kogure, T.;Nagai, Y.
  78. J. Org. Chem. v.52 Onopchenko, A.;Sabourin, E. T.
  79. Organometallics v.6 Brown-Wensley, K. A.
  80. Angew. Chem., Int. Ed. Engl. v.26 Zybill, C.;Muller, G.
  81. Organometallics v.7 Zybill, C.;Muller, G.
  82. Angew. Chem., Int. Ed. Engl. v.28 Zybill, C.;Wilkinson, D. L.;Leis, C.;Muller, G.
  83. Angew. Chem., Int. Ed. Engl. v.27 Zybill, C.;Wilkinson, D. L.;Muller, G.
  84. J. Am. Chem. Soc. v.110 Ueno, K.;Tobita, H.;Shimoi, M.;Ogino, H.
  85. J. Am. Chem. Soc. v.109 Straus, D. A.;Tilley, T. D.;Rheingold, A. L.;Geib, S. J.
  86. Organometallics v.12 Woo, H.-G.;Harrod, J. F.;Henique, J.;Samuel, E.
  87. Organometallics v.9 Harrod, J. F.;Ziegler, T.;Tschinke, V.
  88. Inorganic and Organometallic Oligomers and Polymer Woo, H.-G.;Tilley, T. D.
  89. J. Am. Chem. Soc. v.114 Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  90. Organometallics v.10 Nolan, S. P.;Porchia, M.;Marks, T. J.
  91. J. Am. Chem. Soc. v.114 Harrison, K. N.;Marks, T. J.
  92. J. Am. Chem. Soc. v.114 Gagne, M. R.;Stem, C. L.;Marks, T. J.
  93. J. Am. Chem. Soc. v.114 Conticello, V. P.;Brard, L.;Giardello, M. A.;Tsuji, Y.;Sabat, M.;Stern C. L.;Marks, T. J.
  94. Organometallics v.11 Gagne, M. R.;Brard, L.;Conticello, V. P.;Giardello, M. A.;Stern, C. L.;Marks, T. J.
  95. Personal Communication Choi, N.;Tanaka, M.
  96. J. Am. Chem. Soc. v.117 Imori, T.;Lu, V.;Cai, H,.;Tilley, T. D.
  97. J. Am. Chem. Soc. v.119 Etkin, N.;Fermin, M. C.;Stephan, D. W.
  98. Organometallics v.15 Breen, T. L.;Stephan, D. W.
  99. Organometallics v.15 Breen, T. L.;Steophan, D. W.
  100. Organometallics v.10 Banovetz, J. P.;Stein, K. M.;Waymouth, R. M.
  101. J. Organomet. Chem. v.439 Corey, J. Y.;Zhu, X.-H.
  102. J. Organomet. Chem. v.503 Shaltout, R. M.;Corey, J. Y.;Rath, N. P.
  103. Main Group Chem. v.1 Shaltout, R. M.;Corey, J. Y.
  104. Tetrahedron v.51 Shaltout, R. M.;Corey, J. Y.
  105. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.32 no.1 Gauvin, F.;Harrod, J. F.
  106. J. Am. Chem. Soc. v.110 Bianconi, P. A.;Weidman, T. W.
  107. Organometallics v.6 Corey, J. Y.;Chang, L. S.;Corey, E. R.
  108. Organometallics v.8 Chang, L. S.;Corey, J. Y.
  109. Organometallics v.12 Banovetz, J. P.;Suzuki, H.;Waymouth, R. M.
  110. J. Organomeet. Chem. v.521 Hengge, E.;Gspaltl, P.;Pinter, E.
  111. J. Organomet. Chem. v.443 Hengge, E.;Weinberg, M.
  112. J. Organomet. Chem. v.441 Hengge, E.;Weinberg, M.
  113. J. Organomet. Chem. v.433 Hengge, E.;Weinberg, M.
  114. Macromolecules v.24 Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  115. Chem. Mater. v.5 Imori, T.;Woo, H.-G.;Walzer, J. F.;Tilley, T. D.
  116. J. Am. Chem. Soc. v.115 Banovetz, J. P.;Hsiao, Y.-L.;Waymouth, R. M.
  117. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.34 no.1 Banovetz, J. P.;Hsiao, Y.-L.;Waymouth, R. M.
  118. J. Am. Chem. Soc. v.116 Hsiao, Y.-L.;Waymouth, R. M.
  119. J. Am. Ceram. Soc. v.75 Seyferth, D.;Wood, T. G.;Tracy, H. J.;Robison, J. L.
  120. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) v.34 no.1 Seyferth, D.;Koppetsch, G. E.;Wood, T. G.;Tracy, H. J.;Robison, J. L.;Czubarow, P.;Tasi, M.;Woo, H.-G.
  121. Chem. Mater. v.7 Seyferth, D.;Tasi, M.;Woo, H.-G.
  122. Chem. Mater. v.6 Corriu, R. J. P.;Enders, M.;Huille, S.;Moreau, J. E.