Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Reactions of Phosphites with Nitroalkene Derivatives: Syntheses of $\beta$-Keto Phosphonates and $\alpha$-Cyanoalkylphosphonates

  • Published : 1997.09.20
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Abstract

The addition of phosphite derivatives 1 to nitroalkenes 2 afforded α-phosphoryl nitronates which, on treatment MCPBA, were converted β-keto phosphonates 3. A versatile reaction conditions to generate α-phosphoryl nitronates were examined. α-Cyanoalkylphosphonates 6 were prepared from the diethyl trimethylsilyl phosphite (DTSP) 1c with nitroalkenes 2 and followed by reduction.

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References

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