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Simultaneous Observation of Fe-F and F-Fe-F Stretching Vibrations of Fluoride Anion Ligated Tetraphenylporphyrin Iron(Ⅲ) by Resonance Raman Spectroscopy

  • 발행 : 1997.07.20

초록

Monofluoroiron(Ⅲ) tetraphenylporphyrin, Fe(TPP)F, and difluoroiron(Ⅲ) tetraphenylporphyrin, [Fe(TPP)F2]- were generated in a various non-aqueous solvents by the reaction between Fe(TPP)Cl and tetrabutylammonium fluoride TBAF 3H2O. Formation of the these complexes was detected by the appearance of the ν(F-Fe) (ν, stretching vibration) at 506 cm-1 for Fe(TPP)F and the ν(F-Fe-F) at 448 cm-1 for [Fe(TPP)F2]-, simultaneously, with 441.6 nm excitation by Resonance Raman (RR) spectroscopy. These assignments were confirmed by observed frequency shifts due to 56Fe/54Fe and TPP/TPP-d8/TPP-N15 isotopic substitutions. Difluoroiron complex is an iron(Ⅲ) high-spin complex with the oxidation sensitive band at 1347 cm-1 for ν4 and core size/spin state sensitive band at 1541 cm-1 for ν2.

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참고문헌

  1. The Porphyrins v.6 Hewson, W. D.;Hager, L. P.;Dolphin, D.(Ed.)
  2. Inorg. Chem. v.22 Kadish, K. M.;Rhodes, R. K.
  3. J. Am. Chem. Soc. v.110 Hickman, D. L.;Nanthakumar, A.;Goff, H. M.
  4. Inorg. Chem. v.22 Hickman, D. L.;Goff, H. M.
  5. J. Am. Chem. Soc. v.112 Nanthakumar, A.;Goff, H. M.
  6. Inorg. Chem. v.20 Bottomley, L. A.;Kadish, K. M.
  7. Iron Prophyrins Sprio, T. G.;Lever, A. B. P.(ed.);Gray, H. B.(ed.)
  8. Biological Application of Raman Spectroscopy v.3 Yu, N. T.;Kerr, E. A.;Spiro, T. G.(Ed.)
  9. Biochim. Biophys. Acta v.320 Momenteau, J.;Mispelter, J.;Lexa, D.
  10. Polyhedron v.1 Gans, P.;Marchon, J. C.;Moulis, J. M.
  11. Inorg. Chem. v.20 Anzai, K.;Hatano, K.;Lee, Y. J.;Scheidt, W. R.
  12. J. Raman Spec. v.28 Paeng, I. R.;Nam, H.;Lee, S. W.;Paeng, K.-J.
  13. Bull. Korean Chem. Soc. v.16 Paeng, I. R.;Paeng, K. J.
  14. J. Am. Chem. Soc. v.112 Paeng, I. R.;Nakamoto, K.
  15. Synthesis v.6 Longo, F. R.;Finarelli, M. G.;Kim, J. B.
  16. Porphyrins and Metalloporphyrins Smith, K. M.(Ed.)
  17. Tetrahedron Lett v.48 Rousseau, K.;Dolphin, D.
  18. Inorganic Synthesis v.20 Chang, C. K.;Di Nello, R. R.;Dolphin, D.;Busch, D. H.(Ed.)
  19. Porphyrins and Metalloporphyrins Buchler, J. W.;Smith, K. M.(Ed.)
  20. The Donor-Acceptor Approach to Molecular Ineractions Gutman, V
  21. J. Am. Chem. Soc. v.100 Bruke, J. M.;Kincaid, J. R.;Peters, S.;Gange, R. R.;Collman, J. P.;Sprio, T. G.
  22. Inorg. Chem. v.20 Chottard, G.;Battioni, P.;Battioni, J. P.;Lange, M.;Mansuy, D.
  23. Spectrochim. Acta, Part A v.40 Oshio, H.;Ama, T.;Watanabe, T.;Kincaid, J. R.;Nakamoto, K.
  24. J. Phys. Chem. v.88 Stein, P.;Ulman, A.;Spiro, T. G.