Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Molecular Composite Prepared from Layered Perovskite Oxide, $HLa_2Ti_2NbO_{10}$

  • Published : 1997.06.20
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Abstract

A layered perovskite oxide, $RbLa_2Ti_2NbO_{10}$, was prepared and investigated for proton exchange and intercalation behaviors. Its protonated form, $Hla_2Ti_2NbO_{10}$, exhibits the Bronsted acidity and reacts with organic amines. Polyoxonuclear cation, 4Al_{13}$, was then introduced into the interlayer by refluxing octylamine-intercalated compound with an $Al_{13}$ pillaring solution. These layered oxides were characterized by X-ray diffractometer, thermogravimeter, FT-infrared spectrometer and elemental analyzer. It is observed that the polyoxonuclear cation-pillared material exhibits a bilayer structure and is thermally more stable than organic counterpart at higher temperatures. The surface area of the pillared material annealed at 400 ℃ was the value of 25.1 m²/g.

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