DOI QR코드

DOI QR Code

Molecular Enginering. Container Hosts Having Eight Undecyl Substituents Have High Solubility in Chlorinated Solvents

  • Published : 1997.01.20

Abstract

Nine new solubility-increased container hosts having eight undecyl substituents were synthesized and characterized. 1H NMR spectral data showed integral inclusion state of carceplexes and their stability. 1H NMR chemical shifts of guest DMA were correlated to the host's cavity dimensions shrinked by constrictive binding. Carceplex and hemicarcerand showed their distinctive FD mass spectra.

Keywords

References

  1. Container Molecules and Their Guests Cram, D. J.;Cram, J. M.
  2. J. Am. Chem. Soc. v.110 Cram, D. J.;Karbach, S.;Kim, Y. H.;Baczynskyj, L.;Marti, K.;Smpson, R. M.;Kalleymeyn, G. W.
  3. J. Am. Chem. Soc. v.113 Bryant, J. A.;Blanda, M. T.;Vincenti, M.;Cram, D. J.
  4. J. Am. Chem. Soc. v.113 Sherman, J. C.;Knobler, C. B.;Cram, D. J.
  5. J. Am. Chem. Soc. v.113 Cram, D. J.;Tanner, M. E.;Knobler, C. B.
  6. Angew. Chem. Int. Ed. Engl. v.30 Cram, D. J.;Tanner, M. E.;Thomas, R.
  7. J. Am. Chem. Soc. v.116 Robbins, T. A.;Knobler, C. B.;Bellow, D. R.;Cram, D. J.
  8. J. Am. Chem. Soc. v.117 Kurdistani, S. K.;Helgeson, R. C.;Cram, D. J.
  9. J. Am. Chem. Soc. v.114 Cram, D. J.;Blanda, M. T.;Paek, K.;Knobler, C. B.
  10. Science v.273 Houk, K. N.;Nakamura, K.;Sheu, C.;Keating, A. E.
  11. J. Am. Chem. Soc. v.115 Cram, D. J.;Jaeger, R.;Deshayes, K.
  12. J. Chem. Soc., Chem. Commun. Byun, Y.-S.;Vadhat, O.;Blanda, M. T.;Knobler, C. B.;Cram, D. J.
  13. J. Am. Chem. Soc. v.113 Kuribara, K.;Ohto, K.;Tanaka, Y.;Aoyama, Y.;Kunitake, T.
  14. J. Am. Chem. Soc. v.114 Kobayashi, K.;Asakawa, Y.;Kato, Y.;Aoyama, Y.
  15. J. Am. Chem. Soc. v.116 Chapman, R. G.;Chopra, N.;Cochien, E. D.;Sherman, J. C.
  16. J. Am. Chem. Soc. v.118 Helgeson, R. C.;Paek, K.;Knobler, C. B.;Maverick, E. F.;Cram, D. J.
  17. Bull. Korean. Chem. Soc. v.16 Paek, K.;Joo, K.;Kim, M.;Kim, Y.
  18. Agew. Chem. Int. Ed. Engl. v.33 Timmerman, P.;Verboom, W.;van Veggel, F. C. J. M.;van Duynhoven, J. P. M.;Reinhoudt, D. N.