알루미나에 의한 Fission 몰리브덴의 흡착과 탈착 특성

Adsorption and Desorption Characteristics of Fission Molybdenum on Alumina

Mo-99(Molybdenum) is the only source of Tc-99m(Technetium) which is most frequently used in nuclear medical diagnostics and the demand is on the increase recently. Separation and refining of Mo-99 was investigated by adsorption and desorption on alumina. At pH=0.63, adsorption isotherm of Mo was fitted by Redlich ＆ Peterson equation using the adsorption experimental data. It was found that the pore diffusion model ($D_p=1.4{\times}10^{-6}cm^2/s, K_f/=0.4 cm/s$) agreed well with batch adsorption experimental data. RTDs(Residence Time Distributions ) were measured and axial dispersion coefficients were obtained in the fixed bed absorber according to the changes of the flow rate using 0.05% -NaCl. From the adsorption experimental data, it was shown that the behavior of breakthroughs depended on flow rate. Mo recovery yield was increased as adsorption flow rate was increased and desorption flow rate was decreased.