김해평야에 분포한 특이산성토 중 유황의 형태별 분포 및 Jarosite의 특성

  • 정필균 (농업과학기술원 토양관리과) ;
  • 장용선 (농업과학기술원 토양관리과) ;
  • 신제성 (농업과학기술원 토양관리과) ;
  • 류순호 (서울대학교 농업생명과학대학)
  • Published : 1997.06.01

Abstract

Acid sulfate soils occur in the Gimhae plain where they have been formed from brackish alluvial sediments along the sea coast and river estuary. Acid sulfate soils suffer extremely acidity as a result of oxidation of pyrite. Total sulfur content of the soils was the highest in B horizon of Gimhae series and the lowest in A horizon of Deunggu series. The dominant fractions of sulfur in the soils were jarosite-S for Gimhae series, pyrite-S for Bongrim and Haecheog series, and organic-S for Deunggu series. The essential chemical processes of acid sulfate soils are, firstly, the formation of pyrite in waterlogged environment, and subsequently, the oxidation of this pyrite following natural or artificial drainage. Jarosite [K Fe3(SO4)2(OH)6] is a common sulfur mineral of the oxidation condition. Jarosite shows cubic particles with tetrahedral faces.

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