Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
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A FULL CHARGE SEPARATION OVER THE TWO SAME CHROMOPHORES IN A PHOTOSYNTHETIC TETRAD

  • Published : 1997.09.01
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Abstract

The synthesis and excited-state dynamics are described for a tetrad (ZC - ZP - ZP - I) consisting of zinc chlorin (ZC), zinc porphyrin (ZP), zinc porphyrin (ZP), and pyromellitimide (I), which upon photoexcitation provides a fully charge-separated state (ZC$^+$- P - ZP - l$^- $) with lifetimes of 230 $\mu$s in THF and > 50$ \mu$s in DMF at room temperature via a stepwise electron-transfer relay that has been detected by the ps-time resolved transient absorption spectroscopy.

Keywords

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