Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Studies on Synthesis of 1,2- and 1,3-Diamine Derivatives: Synthesis and Molecular Structure of 3-(N-Benzylamino)-4,5-dihydro-1,2,5-thiadiazole 1,1-dioxides

1,2- 그리고 1,3-디아민 유도체의 합성에 관한 연구(Ⅰ): 3-(N-벤질아미노)-4,4-디히드로-1,2,5-티아디아졸 1,1-디옥시드의 합성과 분자구조

  • Published : 19960700
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Abstract

3-(N-Alkylamino)-4,5-dihydro-1,2,5-thiadiazole 1,1-dioxides have been prepared by the treatment of 3-imino-1,2,5-thiadiazolidine 1,1-dioxides with alkylamines. The selected spectral properties of these heterocycles are detailed, as well as an X-ray crystallographic structure of a representative member of these compounds. 3-(N-Benzylamino)-4,5-dihydro-4-(4'-methoxyphenyl)-1,2,5-thiadiazole 1,1-dioxide crystallyzes in space group $P2_1a$, monoclinic, with $a=22.512(3)(1)\AA$, $b=9.831(2)\AA$, $c=7.194(4)\AA$, $\beta=96.65(2)$, and Z=4.

3-Imino-1, 2, 5-thiadiazolidine 1, 1-dioxide와alkylamine 의 반응에 의하여 3-(N-alkylamino)-4, 5-dihydro-1, 2, 5-thiadiazole 1, 1-dioxide를 제조하였다. 이 헤테로고리 화합물의 주요 분광학적 성질과 X-선 결정학외절에 의한 분자구조를밝혔다. 3-(N-benzylamino)-4, 5-dihydro-4-(4'-methoxyphenyl)-1, 2, 5-thiadiazole 1, 1-dioxide의 단결정은 단사정계, 공간군은 $P2_1a$, $a=22.512(3)(1)\AA$, $b=9.831(2)\AA$, $c=7.194(4)\AA$, $\beta=96.65(2)$, 그리고 Z=4이다.

Keywords

References

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