Synthesis of New Cyanomethyl-1,3,5-triazine Derivatives

새로운 Cyanomethyl-1,3,5-triazine 유도체들의 합성

  • 김정환 (영남대학교 이과대학 화학과) ;
  • 김은주 (영남대학교 이과대학 화학과)
  • Published : 19961100

Abstract

New 6-cyanomethyl-1,3,5-triazine derivatives 4 containing amino, n-propylamino, isopropylamino and anilino groups at 2-and 4-position on the 6-cyanomethyl-1,3,5-triazine ring were prepared from 6-chloro-l,3,5-triazine derivatives 2' and 3 with tert-butyl cyanoacetate. The derivatives of 6-chloro-l,3,5-triazine 2' and 3 containing amino, n-propylamino, isopropylamino and anilino groups at 2- and 4-position on the 6-chloro-1,3,5-triazine ring were prepared from 2,4,6-trichloro-1,3,5-triazine as well as 4,6-dichloro-1,3,5-triazine derivatives 2 with amine derivatives.

6-Cyanomethyl-1, 3, 5-triazine의 2번과 4번 위치에 amino, n-propylamino, isopropylamino, 및 anilino기가 도입된 새로운 유도체 4들의 합성은 6-chloro-1, 3, 5-triazine 유도체 2'들과 3들을 tert-butyl cyanoacetate로 반응시켜 얻었으며, 6-chloro-1, 3, 5-triazine의 2번과 4번 위치에 amino, n-propylamino, isopropylamino, 및 anilino기가 도입된 유도체 2'들과 3들은 2, 4, 6-trichloro-1, 3, 5-triazine 및 4, 6-dichloro-1, 3, 5-triazine 유도체 2들과 amine 유도체들로부터 합성되었다.

Keywords

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