Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Chemical Reactions in Solid State Complexes of 1,2-Polybutadiene and Palladium Chloride : High Temperature Infrared Study

  • Published : 1996.09.20
Download PDF
⟨ Previous Next ⟩

Abstract

Fourier transform infrared (FTIR) temperature studies were performed to examine the microstructural changes that occur in annealing process of the thin films of 1,2-polybutadiene (1,2-PBu)/palladium chloride (PdCl2) complex. The disappearance of the infrared absorption intensities at 1640, 1418, 994 and 910 cm-1 signifies the consumption of 1,2-vinyl groups of 1,2-PBu. The progressive loss of unsaturation and production of methyl groups as a function of temperature were identified by the enhanced infrared absorption intensities at 1447 and 1375 cm-1. The loss of pendent carbon-carbon double bond is considered to involve both palladium-catalyzed addition reaction and thermally induced cyclization.

Keywords

References

  1. Macromolecules v.28 Bosse, F.;Das, P.;Belfiore, L. A.
  2. Polym. International v.36 Bosse, F.;Das, P.;Belfiore, L. A.
  3. J. Polym. Sci., Polym. Phys. Ed. Bosse, F.;Das, P.;Belfiore, L. A.
  4. Macromol. Sympo. v.80 Sherrington, D. C.;Tang, H. .G.
  5. Br. Bolym. J. v.22 Mani, R.;Mahadevan, V.;Srinivasan, M.
  6. J. Polym. Sci. v.A-1 Kaplan, M. L.;Kelleher, P. G.
  7. J. Polym. Sci., Polym. Chem. Ed. v.19 Golub, M. A.
  8. The Vibrational Spectroscopy of Polymers Bower, D. I.;Maddams, W. F.
  9. Macromolecules v.2 Golub, M. A.
  10. J. Polym. Chem. Polym. Lett. Ed. v.11 Golub, M. A.;Sung, M.
  11. J. Polym. Sci., Polym. Lett. Ed. v.12 Golub, M. A.
  12. J. Polym. Sci., Polym. Chem. v.18 Golub, M. A.;Rosenberg, M. L.
  13. Chemical Modification of Natural and Synthetic Polymers Lazar, M.;Bleha, T.;Rychly, J.
  14. J. Polym. Sci., Polym. Chem. Ed. v.12 von Raven, A.;Heusinger, H.