Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Analysis of Rotationally Cooled Vibronic Emission Spectra ($1^2A_2→1^2B_2$) of m-Xylyl Radical

  • Published : 1996.08.20
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Abstract

The rotationally cooled but electronically excited m-xylyl radical has been generated in a jet from the gas mixture of precursor m-xylene and buffer gas He by a technique of corona excited supersonic expansion. The visible vibronic emission spectra in the transition of 12A2→12B2 of m-xylyl radical in the gas phase have been recorded using a Fourier transform spectrometer. The spectra have been analyzed for the assignments of the vibrational frequencies in the electronic ground state with combination of the torsional frequencies reported previously.

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