DOI QR코드

DOI QR Code

Selective Acylation and Aminomethylation of Benzoylated Calix[4]arene

  • 발행 : 1996.06.20

초록

Two different acyl substituents were introduced at the lower rim of calix[4]arene by the two step reactions. Calix[4]arenes (1) reacted with 3,5-dinitrobenzoyl chloride to yield monosubstituted calix[4]arene (2). Second substitution was achieved by the reaction of 2 with various acyl chlorides. Aminomethylation of monobenzoylated calix[4]arene was conducted successfully in the presence of secondary amine and formaldehyde.

키워드

참고문헌

  1. Royal Society of Chemistry Gutche, C. D. Calixarenes;Stoddart, J. F.(ed.)
  2. Nature v.368 Atwood, J. A.;Koutsantonis, G. A.;Raston, C. L.
  3. J. Org. Chem. v.59 Ferguson, G.;Gallagher, F.;Giunta.;Neri, P.;Pallalardo, S.;Parisi, M.
  4. J. Org. Chem. v.58 Andretti, G. D.;Bohmer, V.;Jordon, J. G.;Tabatabai, M.;Ugozzoli, F.;Vogt, W.;Wolff, A.
  5. J. Am. Chem. Soc. v.113 Groenen, L. C.;van Loon, J. D.;Verboom, W.;Harkema, S.;Casnati, A.;Ungaro, R.;Pochini, A.;Ugozzoli, F.;REinhoudt, D. N.
  6. J. Am. Chem. Soc. v.116 Iwamoto, K.;Shimizu, H.;Araki, K.;Shinkai, S.
  7. Bull. Korean Chem. Soc. v.16 Nam, K. C.;Kim, J. M.;Kim, D. S.
  8. J. Che. Soc. Perkin Trans. v.I Chang, S.-K.;Cho, I.
  9. J. Inclution Phenomena and Molecular Recognition Chemistry v.14 Sakaki, T.;Harada, T.;Deng, G.;Kawabata, H.;Kawahara, Y.;Shinkai, S.
  10. J. Org. Chem. v.57 Gutche, C. D.;See, K. A.
  11. J. Chem. Soc. Chem. Commun. No, K. H.;Hong, M.
  12. J. Bull. Korean Chem. Soc. v.13 Nam, K. C.;Kim, D. S.;Yang, S.
  13. J. Org. Chem. v.56 See, K. A.;Fronczek, F. R.;Watson, W. H.;Kashyap, R. P.;Gutche, C. D.
  14. J. Org. Chem. v.56 Jaime, C.;Mandoza, J. D.;Prados, P.;Nieto, P. M.;Sanchez, C.
  15. J. Org. Chem. v.50 van Loon, J. D.;Arduini, A.;Coppi, L.;Verboom, W.;Pochini, A.;Ungaro, R.;Harkema, S.;Reinhoudt, D. N.