DOI QR코드

DOI QR Code

Preparation of Organosilane Dendrimer Containing Allyl End Groups

  • Published : 1996.05.20

Abstract

A dendrimeric silane containing 162 allylic end groups is prepared via a divergent growing approach. The reaction process of the repetitive alkenylation and hydrosilylation cycles was monitored by NMR spectroscopic attachments. Both steps provided almost quantitative yields of pure silane dendrimers.

Keywords

References

  1. Angew. Chem. v.102 Tomalia, D. A.;Naylor, A. M.;GoddardIII, W. A.
  2. Angew. Chem., Int. Ed. Engl v.29 Tomalia, D. A.;Naylor, A. M.;GoddardIII, W. A.
  3. Angew. Chem. v.106 Issberner, J.;Moors, R.;Vogtle, F.
  4. Angew. Chem., Int. Ed. Engl. v.33 Issberner, J.;Moors, R.;Vogtle, F.
  5. Top. Curr. Chem. v.165 Tomalia, D. A.;Durst, H. D.
  6. Adv. Mater. v.6 Tomalia, D. A.
  7. Angew. Chem. v.104 Mekelburger, H. B.;Jaworek, W.;Vogtle, F.
  8. Angew. Chem., Int. Ed. Engl. v.31 Mekelburger, H. B.;Jaworek, W.;Vogtle, F.
  9. Adv. Mater. v.4 Kim, Y. H.
  10. Angew. Chem. v.105 Worner, C.;Mulhaupt, R.
  11. Ange w. Chem., Int. Ed. Engl. v.32 Worner, C.;Mulhaupt, R.
  12. Angew. Chem. v.105 de Brabander-van den Berg, E. M. M.;Meijer, E. W.
  13. Angew. Chem., Int. Ed. Engl. v.31 de Brabander-van den Berg, E. M. M.;Meijer, E. W.
  14. Chem. Eng. News O'Sullivan, D. A.
  15. J. Am. Chem. Soc. v.114 Hawker, C. J.;Frechet, J. M. J.
  16. J. Am. Chem. Soc. v.112 Hawker, C. J.;Frechet, J. M. J.
  17. J. Am. Chem. Soc. v.113 Wooley, K. L.;Hawker, C. J.;Frechet, J. M. J.
  18. J. Chem. Soc., Chem. Commun. van der Made, A. W.;Van Leeuwen, P. W. N. M.
  19. Adv. Mater. v.5 van der Made, A. W.;van der Leeuwen, P. W. N. M.;Wilde, J. C.;Brandes, R. A. C.
  20. Adv. Mater. v.5 van der Made, A. W.;van der Leeuwen, P. W. N. M.;de Wilde, J. C.;Brandes, R. A. C.
  21. J. Am. Chem. Soc. v.117 Sekiguchi, A.;Nanjo, M.;Kabuto, C.;Sakurai, H.
  22. Organometalics v.13 Seyferth, D.;Son, D. Y.;Rheingold, A. L.;Ostrander, R. L.