Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Structural and Electronic Properties of an Alkali Fulleride, $Rb_1C_{60}$

  • Published : 19960100
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Abstract

Structural and electronic properties of an alkali metal fulleride, Rb1C60, was studied. In spite of the chain structure with shortdistance between balls along the crystallographic a-direction, the electronic structure calculation study with the X-ray defined crystal structure shows that Rb1C60 is a three-dimensional metal at room temperature. This result is different from the magnetic experiments in which the compound was found to behave as a quasi-one-dimensional metal. Partial Fermi surface nesting is supposed to be the reason for the metal-insulator transition found in Rb1C60 at ∼50 K.

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References

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