Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Crystal Structure, and Magnetic Properties of $RbV_2SeO_7$ as Compared with $KV_2SeO_7$

  • Published : 1996.12.20
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Abstract

Crystalline compound RbV2SeO7, a Rb analogue of KV2SeO7, was synthesized from a hydrothermal reaction of V2O5, V2O3, SeO2, and Rb2CO3 in the mole ratio 3: 1: 15: 6 (in millimoles) at 230℃. RbV2SeO7 crystallizes in an orthorhombic space group Pnma (No. 62) with a=18.444(8), b=5.415(3), c=7.070(4) Å, Z=8. The two structures of KV2SeO7 and RbV2SeO7 are almost the same except that bond lengths in the latter are slightly longer than in the former. The magnetic susceptibility measurement for RbV2SeO7 in the temperature range 4-300 K showed an antiferromagnetic ordering with TN=45 K, higher than that for KV2SeO7 of 27 K. The origin of the magnetic coupling and the different ordering temperatures in the two phases are discussed in relation to the crystal structures.

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