과산화수소/글리옥살 산화환원계를 사용한 양모의 염색성

Dyeing Properties of Wool Using Hydrogen Peroxide/Glyoxal Redox System

  • Jeong, Dong Seok (Dept. of Textile Eng., Punsan National Univ., Pusan, Korea) ;
  • Lee, Mun Cheul (Dept. of Clothing and Textiles, Kyungsung Univ., Pusan, Korea) ;
  • Lee, Young Hee (Dept. of Textile Eng., Punsan National Univ., Pusan, Korea) ;
  • Kim, Kyung Hwan (Dept. of Textile Eng., Punsan National Univ., Pusan, Korea)
  • 발행 : 1996.02.01

초록

Wool fabric and merino wool top were dyed with two dyes, C.I. Acid Red 13 and C.I. Direct Blue 1 in presence of hydrogen peroxide/glyoxal redox system at various conditions such as dyeing time, temperature and redox concentration. The pH of dye bath was 4.5 in buffer solution of $KH_{2}PO_{4}$ (0.1mol/1)/$Na_{2}HPO_{4}$ (0.1mol/1). Also dyeing of cotton fabric was carried out with C.I. Direct Blue 1 in absence or presence of redox system. The color depth(K/S) increased with redox concentration and dyeing temperature. The increases in dyeing rate and equilibrium dye exhaustion of Acid Acid 13 and Direct Blue 1 on wool fiber and fabric in the present of hydrogen peroxide/glyoxal have been caused by decreasing in pH value during dyeing process which due to the decomposition of hydrogen ion in glyoxal with the assistance of hydrogen peroxide. But the decreases in exhaustion of Direct Blue 1 on cotton may be attributed to repulsive interac ion between salt and salt.

키워드

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