$Li_2O$.$2SiO_2$유리의 결정화에서 승온속도가 기계적 특성에 미치는 영향

effect of Heating Rate on the Mechanical Properties in the Crystallization of $Li_2O$.$2SiO_2$ Glass

  • 최병현 (국립기술품질원 요업기술원) ;
  • 고경현 (아주대학교 재료공학과) ;
  • 안재환 (아주대학교 재료공학과) ;
  • 지응업 (국립기술품질원 요업기술원)
  • 발행 : 1996.07.01

초록

When Li2O.2SiO2 glass was crystallized between the temperature of maximum nucleation and the temperature of maximum crystal growth it was found that the control of heating rate had serious effect on the crystallinity and microstructure and the greatly changed physical properties. Density and elastic modulus tends to increase but thermal expansion coefficient decreased with increased crystallinity. When heating rate between the tempe-rature of maximum nucleation and the temperature of maximum crystal growth was 10~5$0^{\circ}C$/hr. crystallinity was increased to result in the increment of strength. When nuclation was done at 44$0^{\circ}C$ for 5 hours and the temperature of crystal growth was held at 575$^{\circ}C$ strength was increased until crystallinity reached 65% and strength was decreased with higher crystallinity. These phenomena could be explained that even for the same crystallinity different heat rates resulted in different number and size of cracks.

키워드

참고문헌

  1. Glass Tech. v.15 no.6 Microstructure Development and Crystallization Kinetics of Lead Titanate Forming From a PbO-TiO₂-Al₂O₃-SiO₂ Glass M.A.C.G. van de Graaf;J.C. Lodder;A.J. Burggraaf
  2. Bull Govt. Ind. Res. Inst Osaka v.12 Studies on Fine Gramed Crystalline Glass-Ceramics: Studies on the Submicro-Crystallization of Li₂O·2SiO₂ Glass by Addition of (TEX)$P₂O_5$(/TEX) (Ⅰ) K. Nagaoka;M. Hara;H. Tanaka
  3. J. Am. Ceram. Soc. v.66 no.3 Effect of Thermal History on the Properties of Willemite Glass-Ceramics J.E. Shelby;M.C. Nichols
  4. J. Am. Ceram. Soc v.55 no.2 Effect of Crystallization on the Mechanical Properties of Li₂O-SiO₂ Glass-Ceramics S.W. Freiman;L.L. Hench
  5. J. Am. Ceram. Soc. v.53 no.5 Strength of Glass-Ceramics Relative to Crystal Size Y. Utsumi;S. Sakka
  6. J. Am. Ceram. Soc. v.49 no.2 Proposed Fracture Theory of a Dispersion-Stregthened Glass Matrix D.P. Hasselman;R.M. Fulrath
  7. J Am. Ceram. Soc. v.50 no.8 Micromechanical Stress Concentrations in Two-Phase Brittle-Matrix Ceramic Composites D.P. Hasselman;R.M. Fulrath
  8. J. Am. Ceram. Soc. v.60 no.1;2 Dispersion-strengthened Glass Matrices-Glass-Ceramics, a Case in Point M.P. Borom
  9. J. Am. Ceram. Soc v.58 no.9;10 Strength and Microstructure in Littium Disilicate Glass-Ceramics M.P. Borom
  10. J. Mat. Sci. v.7 Theoretical Approach to the Fracture of Two-Phase Glass-Crystal Composites N. Miyata;H. Jinno
  11. J. Am. Ceram. Soc. v.66 no.10 Effect of Crystallites on Surface Damage and Fractrue Behavior of a Glass-Ceramic R. Morena;K. Niihara;D.P.H. Hasselman
  12. J. Mat. Sci v.11 Glass-Ceramics with Random and Oriented Microstructures D.I.H. Atkinson;P.W. Mcmillan
  13. Advances in Ceramics v.4 Fracture Mechanics Analysis of Glass-Ceramics J.J. Mccholsky
  14. J Mat. Sci v.2 Mechanical Properties of Selected Glass-Crystal Composites W.J. Frey;J.D. Mackenzie
  15. J. Non-Cryst. Solids v.34 A Test of Classical Nucleation Theory:Crystal Nucleation of Lithium disilicate Glass G.F. Neilson;M.C. Weinberg
  16. J. Japan Ceram. Soc. v.81 no.11 Rate of Crystal Growth in Li₂O·2SiO₂ Glass K. Matusita;M. Tashiro
  17. J. Kor. Ceram. Soc. v.27 no.4 Li₂O·2SiO₂유리의 결정화와 투광성에 관한 연구 최병현;안재환;지응입
  18. J. Chem. Phys. v.9 Granulation Phase Change and Microstructure:Kinetics of Phase ChangeⅢ M. Avrami