Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Infinite Framework Material Composed of 4,4 -Bipyridine: Shape-selective Clathration of Aromatic Guests

방향족을 형태선택적으로 포접할 수 있는 무한골격물질의 합성에 관한 연구

  • Published : 1996.11.01

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Abstract

Solid materials with inner cavities such as zeolites o(ten promote organic reactions in regio-, stereo-, and shape-selective fashions. Construction of inner cavities in the solid composed mainly of organic components is attractive since the shape, size, and function of the inner cavity become designable. This paper reports the formation and catalysis of a two-dimensional square network material composed of Cd and 4,4'-bipyridine(bay). Since this material has inner cayities surrounded by four 4,4'-bpy units, it easily clathrated some aromatic guests. The crystal structure and a clathrate compound ( ), are measured.

Keywords

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