Bulletin of the Korean Chemical Society

  • 제16권7호
  • /
  • Pages.578-582
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  • 1995
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Ultrasensitive Trace Determination of Pb by Two-Color Resonance Ionization Mass Spectrometry

  • 발행 : 1995.07.20
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초록

The resonance ionization mass spectrometry (RIMS) system with angular reflectron type time-of-flight mass spectrometer (AREF-TOFMS) has been developed and characterized. The system is applied for the ultratrace determination of Pb element. The 2-color 3-photon laser ionization scheme is adopted for the study and the mass resolution of the system is determined as T/ΔT=1680. The calibration curve for Pb is obtained in the range of 100 ppb to 0.01 ppb by using standard solutions. The minimal amount of detection for the present RIMS system is determined as less than 100 femtograms (10-13 gram).

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참고문헌

  1. Principles and Applications of Resonance Ionisation Spectroscopy Hurst, G. S.;Payne, M. G.
  2. Laser Analytical Spectrochemistry Letokhov, V. S.
  3. Resonance Ionization Spectroscopy 1986 Hurst, G. S.(ed.);Morgan, C. G.(ed.)
  4. Anal. Chem. v.61 Bolshov, M. A.;Boutron, C. F;Zybin, A. V.
  5. Proceedings of the fifth International Symposium on Resonance Ionization Spectroscopy and its Applications Burshaw, B. A.;Munley, J. T.;Parks, J. E.(ed.);Omenetto, N.(ed.)
  6. Proceedings of the sixth International Symposium on Resonance Ionization Spectroscopy and its Applications Burshaw, B. A.;Miller, C. M.(ed.);Parks, J. E.(ed.)
  7. J. Kor. Chem. Soc. v.36 Song, K.;Yi, J. H.;Lee, J. M.
  8. Phys. Rev. v.7 Saloman, E. B.;Happer, W.