Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

A Theoretical Treatment of the Resonances in the Predissociation of Lower Rovibrational Levels of the $A^2\Sigma^+$ State of OH

  • Published : 19950500
Download PDF
⟨ Previous Next ⟩

Abstract

An exact quantum mechanical theory is employed to treat predissociation process of the $A^2{\Sigma}^+$ state of OH. The widths and positions of the lower (v= 2 and v= 3) rovibrational levels are calculated. Energy shifts of the resonances from the zeroth order (pure Hund'scase (b)) positions are shown to be small for N $\leq$ 10, indicating that the $A^2{\Sigma}^+$ state can be described as case (b) very well for low N. Due to the differential interactions of the $A^2{\Sigma}^+_{1/2}$ and $A^2{\Sigma}^+_{-1/2}$ states with $X^2II$and $2^2II$ states, small splittings between the $F_1$ and $F_2$ levels are predicted. Calculated lifetimes of the resonances agree with experimental results reasonably well.

Keywords

References

  1. J. Chem. Phys. v.79 Dishoeck, E.F.;Dalgarno, A.
  2. J. Chem. Phys. v.97 Yarkony, D.R.
  3. J. Chem. Phys. v.81 Dishoeck, E.F.;Hemert, M.C.;Allison, A.C.;Dalgarno, A.
  4. J. Chem. Phys. v.77 Langhoff, S.R.;Dishoeck, E.F.;Wetmore, R.;Dalgarno, A.
  5. J. Chem. Phys. v.78 Dishoeck, E.F.;Langhoff, S.R.;Dalgarno, A.
  6. J. Chem. Phys. v.95 Gray, J.A.;Farrow, R.L.
  7. J. Chem. Phys. v.96 Heard, D.E.;Crosley, D.R.;Jeffries, J.B.;Smith, G.P.;Hirano, A.
  8. J. Chem. Phys. v.87 Bauslicher, C.W.;Langhoff, S.R.
  9. Phys. Rev. A. v.47 Iwai, M.;Lee, S.;Nakamura, H.
  10. in Molecules in Laser Fields Lee, S.;Iwai, M.;Nakamira, H.
  11. Chem. Phys. Lett. v.65 Sink, M.L.;Bandrauk, A.
  12. J. Chem. Phys. v.73 Sink, M.L.;Bandrauk, A.
  13. Phys. Rev. v.124 Fano, U.
  14. J. Chem. Phys. v.99 Kim, B.;Yoshihara, K.
  15. Phys. Rev. Lett. v.73 Kim, B.;Yoshihara, K.;Lee, S.
  16. J. Chem. Phys. v.97 Brandon, J.T.;Reid, S.A.;Robie, D.C.;Reisler, H.
  17. Bull. Chem. Soc. v.16 Lee, S.
  18. Chem. Phys. Lett. Lee, S.
  19. J. Chem. Phys. Lee, S.
  20. submitted for publication Lee, S.
  21. J. Chem. Phys. v.67 Johnson, B.R.
  22. Math. Comp. v.383 Cooley, J.W.
  23. J. Chem. Phys. v.34 Fallon, K.J.;Tobias, J.;Vanderslice, J.T.
  24. J. Chm. Phys. v.66 Horsley, J.A.;Richards, W.G.
  25. Spectra of Diatomic Molecules Herzberg, G.
  26. Perturbations in the Spectra of Diatomic Molecules Lefebvre-Brion, H.;Field, R.W.
  27. Phys. Scr. v.17 Brzozowski, T.;Erman, P.;Lyyra, M.
  28. Phys. Scr. v.23 Bergeman, T.;Erman, P.;Haratym. Z.;Larasson, M.
  29. Chem. Phys. Lett. v.130 Lee, S.;Williams, C.J.;Freed, K.F.
  30. J. Chem. Phys. v.87 Lee, S.;Freed, K.F.