Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Kinetic Studies on the Reaction of the Heterobimetallic Anion, $(OC)_5CrMn(CO)_5{^-}M^+\;(M^+=Na^+,\;PPN^+)$ with Allyl Bromide

  • Published : 1995.04.20
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Abstract

The heterobimetallic anion, (OC)5CrMn(CO)5-M+ (M+=Na+, PPN+), which has a donor-acceptor metal-metal bond1, was reacted with allyl bromide to yield BrCr(CO)5- and Mn(CO)5(CH2CHCH2). The reaction mechanism has been proposed in terms of the consecutive reaction pathway in which Cr(CO)5(THF) is an important intermediate leading to the corresponding product. Counterion effect on this reaction was also evaluated and the results were compared with those of the corresponding reaction of the mononuclear carbonyl anion, Mn(CO)5-.

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References

  1. J. Chem. Soc., Chem. Commun. Einstein, F. W. B.;Pomeroy, P. K.;Rushman, P.;Willis, A. C.
  2. Organometallics v.8 Davies, H. B.;einstein, F. W. B.;Glavina, P. C.;Jones, T.;Pomery, R. K.;Rushman, P.
  3. J. Am. Chem. Soc. v.108 Arndt, L. W.;Darensbourg, M. Y.;Delord, T.;Bancroft, B. T.
  4. Inorg. Chem. v.32 Michos, D.;Luo, X. L.;Crabtree, R. H.
  5. Inorg. Chim. Acta v.198 Holstetler, M. J.;Butts, M. D.;Bergman, R. G.
  6. J. Am. Chem. Soc. v.111 Ozwa, F.;Park, J. W.;Mackenzie, P. B.;Schaefer, W. P.;Henling, L. M.;Crubbs, R. H.
  7. J. Organomet. Chem. v.387 Casey, C. P.;Askham, F. R.;Petrovich, L. M.
  8. J. Organomet. Chem. v.408 Park, Y. K.;Kim, S. J.;Kim, J. H.;Han, I. S.;Lee, C. H.;Choi, H. S.
  9. Bull. Kor. Chem. Soc. v.11 Park. Y. K.;Han, I. S.;Huh, T. S.
  10. J. Am. Chem. Soc. v.89 Ander, U.;Graham, W. A. G.
  11. Inorg. Chem. v.7 Ruff, J. K.
  12. J. Am. Chem. Soc. v.106 Arndt, L. W.;Delord, T.;Darensbourg, M. Y.
  13. J. Am. Chem. Soc. v.107 Gaus, P. L.;Kao, S. C.;Youngdahl, K.;Darensbourg, M. Y.
  14. J. Am. Chem. Soc. v.88 Hayter, R. G.
  15. Inorg. Chem. v.3 Flitcroft, N.;Huggins, D. K.;Kaesz, H. D.
  16. Inorg. Chem. v.26 Einstein, F. W. B.;Jennings, M. C.;Krentz, R.;Pomeroy, R. K.;Rushman, P.;WIllis, A. C.
  17. Inorg. Chem. v.25 Robert, D. A.;William, C. M.;Geoffroy, G. L.;Pierpont, C. G.
  18. Inorg. Chem. v.24 Gelmini, L.;Matassa, L. C.;Stephan, D. W.
  19. Organometallics v.9 Antonelli, D. M.;Cowie, M.
  20. J. Organomet. Chem. v.242 Bruce, M. I.
  21. Inorg. Chem. v.26 Pope, K. R.;Wrighton, M. S.
  22. Inorg. Chim. Acta v.198 Uson, R.;Fornies, J.
  23. Inorg. Chem. v.25 Moulton, R.;Weidman, T. W.;Vollhardt, K. P. C.;Bard, A. J.
  24. Inorg. Chem. v.31 Diemen, J. H.(et al.)
  25. Organometallics v.10 Rausch, M. D.;Ogasa, M.;Ayers, M. A.
  26. J. Organomet. Chem. v.452 Wadepohl, H.;Galm, W.;Wolf, A.
  27. J. Am. Chem. Soc. v.98 Darensbourg, M. Y.;Darensbourg, D. J.;Drew, D. A.;Burns, D.
  28. J. Am. Chem. Soc. v.108 Arndt, L. W.;Darensbourg, M. Y.;Delord, T.;Bancroft, B. T.
  29. Organometallis v.6 Lee, K. Y.;Kuchynka, D. J.;Kochi, J. K.
  30. Organometallics v.4 Kao, S. C.;Spillett, C. T.;Lusk, R.;Park, Y. K.;Darensbourg, M. Y.
  31. Ph. D. Dissertation, Texas A&M Univ. Park. Y. K.
  32. Bull. Kor. Chem. Soc. v.15 Park, Y. K.;Han, I. S.;Darensbourg, M. Y.
  33. Inorg. Chem. v.14 Johnson, J. R.;Duggan, D. M.;Risen Jr., W. M.
  34. Inorg. Chem. v.12 Johnson, J. R.;Ziegler, R. J.;Risen Jr., W. M.
  35. J. Chem. Soc., Dalton Trans. Onaka, S.;Sugawara, T.;Kawada, Y.;Iwamura, H.
  36. Bull. Kor. Chem. Soc. v.15 Park. Y. K.;Han, I. S.;Kim, J. H.;Lee, C. J.;Baek, Y. O.;Song, G. O.
  37. Anal. Biochem. v.217 Pou, S.(et. al.)
  38. J. Am. Chem. Soc. v.104 Darensbourg, M. Y.;Jimenez, P.;Sackett, J. R.;Hankel, J. M.;Kump, R. L.
  39. J. Organomet. Chem. v.202 Darensbourg, M. Y.;Jimenez, P.;Sackett, J. R.
  40. J. Organomet. Chem. v.185 Moro, A.;Foa, M.;Cassar, L.
  41. J. Am. Chem. Soc. v.101 Winston, P. L.;Bergman, R. G.
  42. Bull, Kor. Chem. Soc. v.10 Park, Y. K.;Han, I. S.;Huh, T. S.;Darensbourg, M. Y.
  43. Structural Methods in Inorganic Chemistry(2nd Ed.) Ebsworth, E. A. V.;Rankin, D. W. H.;Cradock, S.