Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Topological Analysis on the Degree of Complexation and Viscosity of Polymer Complexes

  • Published : 1995.11.20
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Abstract

A topological theory has been introduced to evaluate the degree of complexation and the viscosity of polymer complexes by extending the theory of Iliopoulos and Audebert for aqueous polymer solutions. The previous theory of Iliopoulos and Audebert has offered only a semiquantitative theoretical model for polymer complex systems, whereas our present work gives a general theoretical model applicable to all the polymer complex systems. Their theories considered only the physical property term caused by the displacement of complexed points between polymer solute chains, while our theory deals with all the physical effects, caused by the displacement of complexed points entangled points in polymer solute chains. There have been predicted the characteristics of physical properties from the expression. It is exposed that the predictive values show good agreement with the experimental data for polymer complexes.

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References

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