Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Investigation of the Reaction Coordinate for Dissociation in $Cr(CO)_6$ Using Resonance Raman Spectroscopy

  • Published : 1995.11.20
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Abstract

The overtone of the ν2 vibrational mode in Cr(CO)6 are observed for the first time in cyclohexane and methanol at both the 266 and 213 nm excitations. The appearance of the overtones due to the displacement of the electronic excited state with respect to the ground state along the ν2 vibrational mode is interpreted in terms of wavepacket concept and molecular orbital (MO) theory. Our Raman results suggest a new interpretation for the excited state potential.

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References

  1. Inor. Chem. v.14 Burdet, J. K.;Grzybowski, J. M.;Perutz, R. N.;Poliakoff, M.;Turner, J. M.;Tuner, R. F.
  2. J. Phy. Chem. v.94 Adelman, D.;Gerrity, D. P.
  3. Chem. Rev. v.74 Wrighton, M.
  4. J. Phy. Chem. v.90 Simon, J. D.;Xie, X.
  5. J. Am. Chem. Soc. v.110 Wang, L.;Zhu, X.;Spears, K. G.
  6. Chem. Phys. v.152 Joly, A. G.;Nelson, K. A.
  7. J. Am. Chem. Soc. v.111 Lee, M.;Harris, C. B.
  8. J. Am. Chem. Soc. v.112 Yu, S.-C.;Xu, X.;Lingle, R. Jr.;Hopkins, J. B.
  9. J. Phys. Chem. v.94 Chang, Y. J.;Xu, X.;Yabe, T.;Yu, S.-C.;Anderson, D. R.;Orman, L. K.;Hopkins, J. B.
  10. J. Chem. Phys. v.23 Hawkins, N. J.;Mattraw, H. C.;Sabol, W. W.;Carpenter, D. R.
  11. J. Chem. Phys. v.34 Albrecht, A. C.
  12. J. Chem. Phys. v.76 Lee, S. Y.;Heller, E. J.
  13. J. Phys. Chem. v.88 Imre, D.;Kinsey, J. L.;Sinha, A.;Krenos, J.
  14. Inorg. Chem. v.11 Jones, L. H.;McDowell, R. S.;Goldblatt, M.