A Study on the Fabrication of Porous Nickel Substrates Using Graphite Powder

흑연분말을 이용한 다공성 니켈지지체의 제조에 관한 연구

  • 박성용 (화공연구부 전기화학연구팀, 한국과학기술연구원) ;
  • 백지흠 (화공연구부 전기화학연구팀, 한국과학기술연구원) ;
  • 조원일 (화공연구부 전기화학연구팀, 한국과학기술연구원) ;
  • 조병원 (화공연구부 전기화학연구팀, 한국과학기술연구원) ;
  • 윤경석 (화공연구부 전기화학연구팀, 한국과학기술연구원)
  • Published : 1995.10.01

Abstract

A nickel mesh and an expanded nickel sheet were used as a current collector for supporting active materials of cathode in rechargeable batteries, while a porous nickel substrate was extensively studied because of its 3-dimensional structure which has high capabilities for active materials and current collection. Optimum coating conditions were studied by SEM and two step d. c. constant current electrolysis for the graphite coating and electro-plated nickel on an urethane substance which was highly porous and 3-dimensional structure. The density and the porosity of nickel support obtained by using two step current density and 80 ppi urethane substance were 0.38∼0.40 g /㎤ and 94∼96%, respectively. It was possible to fabricate a highly porous and good packable nickel substrate using two step current density and surfactants at sulfamic acid nickel plating bath.

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