Formation of ultra-thin $Ta_{2}O_{5}$ film on thermal silicon nitrides

열적 성장된 실리콘 질화막위에 산화 탄탈륨 초박막의 형성

  • 이재성 (경북대학교 전자전기공학과) ;
  • 류창명 (경북대학교 전자전기공학과) ;
  • 강신원 (경북대학교 전자전기공학과) ;
  • 이정희 (경북대학교 센서기술연구소) ;
  • 이용현 (경북대학교 전자전기공학과)
  • Published : 1995.11.01

Abstract

To obtain high quality of $Ta_{2}O_{5}$ film, two dielectric layers of $Si_{3}N_{4}$ and $Ta_{2}O_{5}$ were subsequently formed on Si wafer. Silicon nitride films were thermally grown in 10 Torr ammonia ambient by R.F induced heating system. The thickness of thermally grown $Si_{3}N_{4}$ film was able to be controlled in the range of tens $\AA$ due to the self-limited growth property. $Ta_{2}O_{5}$ film of 200$\AA$ thickness was then deposited on the as-grown $Si_{3}N_{4}$ film about 25$\AA$ thickness by sputtering method and annealed at $900^{\circ}C$in $O_{2}$ ambient for 1hr. Stoichiometry film was prepared by the annealing in oxygen ambient. Despite the high temperature anneal process, silicon oxide layer was not grown at the interface of the layered films because of the oxidation barrier effect of Si$_{3}$N$_{4}$ film. The fabricated $Ta_{2}O_{5}$/$Si_{3}N_{4}$ film showed low leakage current less than several nA and high dielectric breakdown strength.

Keywords