Synthesis and Characterization of Functional Polyhydroxyethen(I) -Interfacial Synthesis of Poly(hydrowether of bisphenol A)-

기능성 Polyhydroxyether의 합성 및 그 특성에 관한 연구(I) 계면중합에 의한 Poly(hydroxyether of bisphenol A)의 합성-

  • 정재훈 (영남대학교 공과대학 섬유공학과) ;
  • 손태원 (영남대학교 공과대학 섬유공학과)
  • Published : 1995.10.01

Abstract

Relatively high molecular weigh polyhydroxyether(PHE) polymers have been prepared by the interfacial poly-merization of bisphenol A and epichlorohydrin in an aqueous-organic biphasic system. Interfacial synthesis was forind to be an effective method to prepare higher molecular weight Polymer under mild reaction conditions. It has been revealed that the solvating power of the solvent in organic phase is an important factor affecting the molecular weight of PHE in interfacial synthesis. PHE's thus prepared had different values of molecular weight depending on the solubility of the organic phase; the higher the solubility, the higher the molecular weight.

Keywords

References

  1. Polymer v.24 M.M.Coleman;E.J.Moskala
  2. Polym. Eng. Sci. v.23 no.12 A.Garton
  3. Polym. Eng. Sci. v.24 no.2 A.Garton
  4. J. Appl. Polym. Sci. v.27 J.E.Harris;S.H.Goh;D.R.Paul;J.W.Barlow
  5. Polymer v.32 G.Qipeng;P.Xinsheng;W.Zhiji
  6. Polym. Communications v.24 E.J.Moskala;M.M.Coleman
  7. Polym. Eng. Sci. v.24 no.8 J.I.Eguiazabal;M.E.Calahorra;M.M.Cortazar;J.J.Iruin
  8. Encyclopedia of Polymer Science and Engineering(2nd Ed.) v.6 H.F.Mark;N.M.Bikales;C.G.Overberger;G.Menges
  9. Macromolecules v.5 P.W. Morgan
  10. Interfacial Synthesis(Ⅰ) F.Millich;C.E.Carraher,Jr(Ed.)
  11. Interfacial Synthesis(Ⅱ) F.Millich;C.E.Carraher,Jr(Ed.)
  12. J. Macromol. Sci. Chem. v.A15 no.5 A.K.Banthia;D.Lunsford;D.C.Webster;J.E.McGrath
  13. J. Macromol. Sci. Chem. v.A15 no.5 J.S.Riffle;R.G.Freelin;A.K.Banthia;J.E.McGrath
  14. Properties of Polymers D.W. Van Krevelen
  15. J. Polym. Sci., Polym. Chem. Ed. v.32 X.Ning;H.Ishida
  16. J. Macromol. Sci. Chem. v.A15 no.5 Y.Imai
  17. Tetrahedron v.30 A.Mckillop;J.C.Fiaud;R.P.Hug
  18. Organic Synth. v.55 M.Makosza;A.Zonczyk
  19. Polym. Eng. Sci. v.24 no.5 B.S.Morra;R.S.Stein
  20. Properties of Polymers(3rd Ed.) D.W. Van Krevelen