Studies on the On-line Dry-let Wet Spinning of Polyacrylonitrile(III) - Effect of Spinning Conditions on the Fiber Morfhology-

아크릴고분자의 온-라인건습식방사공정에 관한 연구(III) -방사조건이 섬유구조에 미치는 영향-

  • 김병철 (한국과학기술연구원 고분자연구부) ;
  • 민병길 (한국과학기술연구원 고분자연구부, 한국과학기술연구원 고분자연구부, 한국과학기술연구원 고분자연구부, 영남대학교 섬유공학과, 제일합섬 기술연구소)
  • Published : 1995.05.01

Abstract

This study focused on the effect of spinning conditions on the morphology of PAN fiber in the on-line dry-jet wet spinning. The fiber so produced exhibited a very uniform surface structure compared with wet spun fiber. The coagulant composition (the ratio of dimethyl sulfoxide(DMSO) to water) and coagulation temperature proved to be two cardinal facts for determining the fiber structure. The more circular fibers were obtained at low DMSO contents in the coagulation system and at lower coagulation temperature. However, the take-up speed had little effect on the fiber structure.

Keywords

References

  1. Polymer v.21 P.Smith;P.J.Lemstra
  2. J. Polym. Sci. Phys. Ed. v.19 P.Smith;P.J.Lemstra;H.C.Booij
  3. Eur. Pat., Appl. Ep 114,793
  4. Eur. Pat., 0 144 983 A2
  5. 高分子化學 v.18 高橋正夫
  6. Tex. Res. Inst. P.Bajaj;S.K.Munukutla
  7. J. Korean Fiber Soc. v.31 B.C.Kim;S.G.Kim;B.G.Min;T.W.Son;C.J.Lee;D.U.Kim;S.I.Hong;S.S.Kim
  8. J. Korean Fiber Soc. v.31 B.G.Min;B.C.Kim;T.W.Son;C.J.Lee;C.H.Ahn;C.R.Park;Y.H.Park;S.S.Kim
  9. J. Polym. Sci. v.22 P.F.Onyon
  10. J. Am. Chem. Soc. v.65 F.R.Mayo
  11. J. Polym. Sci. v.2 I.M.Kolthoff;W.E.Harris
  12. J. Polym. Sci. v.2 I.M.Kolthoff;W.E.Harris
  13. J. Polym. Sci. v.2 I.M.Kolthoff;W.E.Harris
  14. J. Am. Chem. Soc. v.68 H.R.Synder;J.M.Stewart;R.E.Allen;R.J.Dearborn
  15. J. Am. Chem. Soc. v.68 F.T.Wall;F.W.Banes;G.D.Sands
  16. J. Appl. Polym. Sci. v.13 D.R.Paul
  17. Appl. Polym. Symp. v.25 A.L.Mcpeters;D.R.Paul
  18. J. Appl. Polym. Sci. v.21 A.L.Mcpeters;D.R.Paul
  19. Faserforschung and Textiltechnik v.20 V.Grobe;K.Meyer
  20. Tex. Res. J. v.32 J.P.Craig;J.P.Knudsen;V.F.Holland
  21. Text. Res. J. v.33 R.G.Quynn