Bulletin of the Korean Chemical Society

  • 제15권6호
  • /
  • Pages.424-427
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  • 1994
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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The Effect of Iron Catalysts on the Formation of Alcohol and Ketone in the Biomimetic Oxidation of Cyclohexane

  • Kim Seong-Bo (Korea Research Institute of Chemical Technology) ;
  • Lee Kyu-Wan (Korea Research Institute of Chemical Technology) ;
  • Kim, Yong-Joon (Department of Chemical Engineering, Korea University) ;
  • Hong Seog-In (Department of Chemical Engineering, Korea University)
  • 발행 : 1994.06.20
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초록

Effects of iron compounds in known biomimetic oxidation systems (Gif IV and GoAgg II) have been studied on activity and ketone/alcohol selectivity of cyclohexane oxidation. Both ketone/alcohol ratio and cyclohexane conversion were affected by counter-ion Z of iron compounds Z-Fe. When Z has a more electron withdrawing property, the reactivity is increased and the formation of ketone is favored. From these experimental results, a new mechanism is proposed for the biomimetic oxidation system.

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참고문헌

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피인용 문헌

  1. A reaction kinetic study on the Gif-type biomimetic oxidation of cyclohexane vol.12, pp.2, 1994, https://doi.org/10.1007/bf02705645
  2. The reaction of [Fe(pic)3] with hydrogen peroxide: a UV-visible and EPR spectroscopic study (Hpic = picolinic acid) vol.2005, pp.16, 1994, https://doi.org/10.1039/b504897d