Bulletin of the Korean Chemical Society

  • 제15권5호
  • /
  • Pages.374-378
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  • 1994
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Syntheses and Properties of New Nickel(II) Complexes of 14-Membered Pentaaza Macrocyclic Ligands with C-Nitro and N-Alkyl Pendant Arms

  • 발행 : 1994.05.20
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초록

Square planar nickel(II) complexes with various 1-alkyl derivatives of the 14-membered pentaaza macrocycle 8-methyl-8-nitro-1,3,6,10,13-pentaazacyclotetradecane can be readily prepared by two-step metal template condensation reactions of ethylenediamine, nitroethane, formaldehyde, and appropriate primary alkylamines. In coordinating solvents the nickel (II) complexes form octahedral species containing two axially coordinated solvent molecules and thus show square planar-octahedral equilibrium. The properties of the pentaaza macrocyclic complexes are considerably different from those of the complexes of analogous hexaaza and tetraaza macrocyclic complexes. Synthesis, characterization, and spectroscopic and chemical properties of the new complexes are described.

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참고문헌

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피인용 문헌

  1. Synthesis and Characterization of New Polyaza Non-macrocyclic and Macrocyclic Nickel(II) Complexes Containing One 1,3-Diazacyclohexane Ring vol.34, pp.7, 1994, https://doi.org/10.5012/bkcs.2013.34.7.2125