Bulletin of the Korean Chemical Society

  • 제15권5호
  • /
  • Pages.357-360
  • /
  • 1994
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Subtractively Normalized Interfacial Fourier Transform Infrared Spectroscopic Study of Cyanide Ions at Gold Electrode

  • Son, Dong-Hee (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Kwan (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • 발행 : 1994.05.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The adsorption of cyanide ion on the gold electrode has been investigated by the subtractively normalized interfacial Fourier transform infrared spectroscopy (SNIFTIRS). The observations made by SNIFTIRS were consistent with those obtained by the polarization modulated Fourier transform infrared spectroscopy. According to the surface selection rule, cyanide ion appeared to adsorb on gold via either carbon or nitrogen lone pair electrons assuming a perpendicular orientation with respect to the metal surface. The possibility of presence of bridge-bound species seemed very infeasible. From the ab initio quantum mechanical calculation, adsorbate-to-metal bonding appeared to occur mainly via the $5{\sigma}$ donation from carbon to Au.

키워드

참고문헌

  1. Spectroelectrochemistry Theory and Practice Beden, B.;Lamy, C.;Gale, R. J.(Ed.)
  2. Surf. Sci. v.53 Pritchard, J.;Catterick, T.;Gupta, R. K.
  3. Surf. Sci. v.72 Hoffman, F.;Bradshaw, A. M.
  4. Chem. Phys. Lett. v.26 Fleischmann, M.;Hendra, P. J.;McQuillan, A. J.
  5. Appl. Surf. Sci. v.6 Otto, A.
  6. Anal. Chem. v.38 Mark, H. B.;Pons, B. S.
  7. J. Electroanal. Chem. v.160 Bewick, A.;Kunimatsu, K.;Pons, B. S.;Russell, J. W.
  8. J. Electroanal. Chem. v.140 Kunimatsu, K.
  9. J. Catal. v.71 Golden, W. G.;Dunn, D. S.;Overend, J.
  10. J. Electroanal. Chem. v.160 Pons, S.;Davidson, T.;Bewick, A.
  11. J. Phys. Chem. v.88 Golden, W. G.;Kunimatsu, K.;Seki, H.
  12. J. Electroanal. Chem. v.123 Kotz, R.;Yeager, E.
  13. J. Electroanal. Chem. v.136 Fleischmann, M.;Hill, I. R.;Pemble, M. E.
  14. Surf. Sci. v.158 Kunimatsu, K.;Seki, H.;Golden, W. G.;Gordon Ⅱ, J. G.;Philpott, M. R.
  15. Langmuir v.4 Kunimatsu, K.;Seki, H.;Golden, W. G.;Gordon Ⅱ, J. G.;Philpott, M. R.
  16. Reflectance Spectroscopy Kortum, G.
  17. Appl. Spectrosc. Rev. v.14 Dignam, M. J.;Fedyk, J.
  18. Gaussian 92 Frisch, M. J.;Trucks, G. W.;Head-Gordon, M.;Gill, P. M. W.;Wong, M. W.;Foresman, J. B.;Johnson, B. G.;Schlegel, H. B.;Robb, M. A.;Replogle, E. S.;Gomperts, R.;Andres, J. L.;Raghavachari, K.;Binkley, J. S.;Gonzalez, C.;Martin, R. L.;Fox, D. J.;Defrees, D. J.;Baker, J.;Stewart, J. J. P.;Pople, J. A.
  19. J. Phys. Chem. v.87 Russell, J. W.;Severson, M.;Scanlon, K.;Overend, J.;Bewick, A.
  20. J. Electroanal. Chem. v.280 Anderson, A. B.
  21. Solid State Commun. v.51 Lambert, D. K.
  22. Phys. Rev. Lett. v.50 Lambert, D. K.
  23. J. Chem. Phys. v.89 Lambert, D. K.
  24. J. Phys. Chem. v.86 Ray, N. K.;Anderson, A. B.
  25. J. Phys. Chem. v.93 Mehandru, P. S.;Anderson, A. B.
  26. J. Electroanal. Chem. v.161 Holloway, S.;Norskov, J. K.
  27. J. Phys. Chem. v.95 Ashley, K.;Weinert, F.;Samant, M. G.;Seki, H.;Philpott, M. R.

피인용 문헌

  1. Nucleation and crystal growth in gold electrodeposition from acid solution Part I: Soft gold vol.26, pp.8, 1994, https://doi.org/10.1007/bf00683747
  2. Effects of Ring Substitution on the Binding and Oxidation of Cyanophenols on Au(111) Electrodes vol.100, pp.17, 1994, https://doi.org/10.1021/jp953709e