Removal of Sulfur Dioxide by Cupric Oxide and Reduction of Cupric Sulfate by Hydrogen

산화구리에 의한 이산화황의 제거와 수소에 의한 황산구리의 환원

  • 노용우 (연세대학교 화학공학과) ;
  • 이명철 (연세대학교 화학공학과) ;
  • 이재훈 (연세대학교 화학공학과) ;
  • 이태희 (연세대학교 화학공학과)
  • Published : 1994.06.01

Abstract

The reaction of sulfur dioxide with cupric oxide was investigated over a temperature range of 300-50$0^{\circ}C$, and the regenaration reaction was studied using cupric sulfate and hydrogen over a temperature range of 240-35$0^{\circ}C$ in a fixed bed reactor. The experimental results showed that the efficiencies for elimination and regenaration reactions were maximum at 45$0^{\circ}C$ and at 30$0^{\circ}C$ respectively. In both cases the experimental data could be interpreted properly by shrinking unreacted core model while the chemical reaction is rate controlling step. The reaction rate constants were determined to be 24.88 exp(-6724/RT) (cm/min) for elimination reaction, and 0.0165 exp(-2047/RT)(cm/min ) for regeneration reaction.

Keywords

References

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