Continuous Cocurrent Extraction of Milk Fat by Supercritical Carbon Dioxide

초임계이산화탄소에 의한 유지방의 연속 병류식 추출

  • Lim, Sang-Bin (Dept . of Food Science and Technology , Cheju National University) ;
  • Syed S.H.Rizvi (Dept. of Food Science , Cornell University)
  • Published : 1994.06.01

Abstract

Performance of a continuous cocurrent supercritical fluid extraction column for processing of anhydrous milk fat (AMF) was determined. The extract loading increased and the extraction yield decreased as the superficial velocity of AMF increased. The maximum solubility of AMF in $CO_2$ at 4$0^{\circ}C$/3,500 psig was 0.0195g/g. The increase of the carbon dioxide density enhanced the solubility of milk fat and decreased the cholesterol concentration in the extract. Three operation conditions, such as recycle , reflux, and temperature gradient of extraction column, were tested. More short-chain fatty acvids were extracted by the reflux operation . Longchain fatty acids and thehighest ratio fo long-chain unsaturated to saturated fatty acids were also obtained in the raffinate phase with refluex.

Keywords

References

  1. Dairy chemistry and physics Walstra,P.;Jenness,R.
  2. Engineering and food v.3 Supercritical fluid processing of milk fat Rizvi,S.S.H.;Lim,S.;Nikoopour,H.;Singh,M.;Yu,Z.;Spiess,W.E.L.(ed.);Schubert,H.(ed.)
  3. Food Technol. v.40 Supercritical fluid extraction: fundamental principles and modeling methods Rizvi,S.S.H.;Benado,A.L.;Zollweg,J.A.;Daniels,J.A.
  4. Food Technol. v.40 Supercritical fluid extraction: operating principles and food applications Rizvi,S.S.H.;Daniels,J.A.;Benado,A.L.;Zollweg,J.A.
  5. Mass transfer operations Treybal,R.E.
  6. I & EC Process Design Development v.6 Cocurrent gas-liquid contacting in packed columns Reiss,L.P.
  7. Official methods of analysis (14th ed.) A.O.A.C.
  8. Private communication Lynch,J.;Barbano,D.M.
  9. Dissertation, Deft University of Technology Supercritical fluid extraction of liquid hydrocarbon mixtures de Haan,A.B.
  10. J. Supercritical Fluids v.5 Phase equilibria of oleic acid, methyl oleate, and anhydrous milk fat in SC-CO₂ Yu,Z.R.;Rizvi,S.S.H.;Zollweg,J.A.
  11. J. Chem. Eng. Data v.34 Novel technique to measure equilibria of supercritical solvents and liquid mixtures Lahiere,L.R.;Fair,J.R.
  12. Supercritical fluid extraction : principle and practices McHugh,M.A.;Krukonis,V.J.
  13. IUPAC international thermodynamics of the fluid state-carbon dioxide Angus,S.;Armstrong,B.;de Reuck,K.M.
  14. Agric. Biol. Chem. v.50 Modification of butter oil by extraction with supercritical carbon dioxide Shishikura,A.;Fujimoto,K.;Kaneda,T.;Arai,K.;Saito,S.
  15. Unit operations of chemical engineering, (3th ed.) McCabe,W.H.;Smith,J.C.
  16. Supercritical fluid extraction and chromatography, ACS symposium series 366 Supercritical fluid-adsorbate-adsorbent systems King,J.W.;Eissler,R.L.;Friedrich,J.P.;Charpentier,B.A.(ed.);Sevenants,M.R.(ed.)