Crystal Growth of $LiTaO_3$ and the Effect pf Crucible Type and Atmosphere

$LiTaO_3$ 단결정 성장과 용기 및 분위기의 영향

  • 박승익 (서울대학교 무기재료공학과) ;
  • 채승욱 ((주)대우전자부품 기술관리실) ;
  • 김정돈 (한국과학기술연구원 세라믹스부) ;
  • 주기태 (한국과학기술연구원 세라믹스부) ;
  • 정수진 (서울대학교 무기재료공학과)
  • Published : 1994.01.01

Abstract

LiTaO3 single crystals were growth without cracking using Pt-Rh crucible and Ir crucible. The starting composition to get the melt of congruent melting composition, which has been dependent upon the experimental procedure, was taken after fixing the total growing process by the result of preliminary experiments. The Rh contamination from the Pt-Rh crucible was to be neglected if the crystal had been grown under inert atmosphere, which resulted in the crystal color being slightly yellow. This color was decolored after 24 hour's annealing at 1200℃ under air atmosphere. The optimum conditions for the crystal growing and the diameter control were so dependent upon the crucible material in spite of using the crucible of the same size. The liquid-solid interface of LiTaO3 crystal of 1" diameter has been flat if the rotation speed was 45rpm.

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References

  1. Journal of American Ceramic Society-Discuss and Notes v.48 no.2 Growth of Piezoelectric and Ferroelectric Materials by the Czochralski Technique A.A. Ballman
  2. Journal of Crystal Growth v.24 Czochralski Growth of Large Diameter LiTaO₃Crystals C.D. Brandle;D.C. Miller
  3. Journal of Crystal Growth v.46 Growth of LiTaO₃ Crystal for SAW Device Application T. Fukuda;S. matsumura;H. Hirano;T. Ito
  4. Ferroelectrics v.27 LiTaO₃ Crystals for Commercial SAW TV. IF Filters H. Hirano
  5. Journal of Crystal Growth v.51 Growth Conditions for Large Diameter X-axis LiTaO₃Crystals S. Mutsumura
  6. Journal of Applied Crystallography v.3 Lithium Tantalate Single Crystal Stoichiometry R.L. Barns;J.R. Carruthers
  7. 한국요업학회지 LiTaO₃단결정의 결함연구 김한균;박승익;박현민;정수진
  8. Journal of Physical Chemistry in Solids v.28 Ferroelectric Lithium Tantalate-1. Single Crystal X-ray Diffraction Study at 24°C S.C. Abrahams;J.L. Bernstein
  9. IEEE Characterization of 4-inch LiTaO₃Single Crystals for SAW Device Application K. Yamada;T. Omi;S. Matsumura
  10. Fast Ion Transport in Solids, Solid State Batteries and Devies R.S. Roth;H.S. Parker;W.S. Brower;J.L. Waning
  11. 한국결정성장학회지 v.11 no.2 LiNbO₃의 Congruent 조성에 관한 연구 이성국;이상학;윤의박
  12. Material Research Bulletin v.16 Some New Nonstoichiometric Ferroelectric Phase Appearing Close to LiTaO₃in the Ternary System $Li_2O-Ta_2O_5-(TiO_2)_2$ B. Elouadi;M. Zriouil