PHOTOCHEMISTRY OF 1-(PHENYL)-4-(2-PYRIDYL)-1,3-BUTADIYNE : PHOTOREACTION WITH SOME OLEFINS

  • Kim, Geon-Soo (Department of Chemistry, The Korea Advanced institute of Science and Technology) ;
  • Kim, Soon-Nam (Department of Chemistry, The Korea Advanced institute of Science and Technology) ;
  • Shim, Sang-Chul (Department of Chemistry, The Korea Advanced institute of Science and Technology)
  • Published : 1994.03.01

Abstract

Irradiation of 1-phenyl-4-(2-pyridyl)-1,3-butadiyne (2-PPB) with dimethyl fumarate (DMFu) and 2,3-dimethyl-2-butene (DMB) yields photoadducts, 1-12. The mechanism of the photoreaction of 2-PPB with olefins is similar to that of 1,4-diphenyl-1,3-butadiyne with oiefins.

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