한국산업보건학회지 (Journal of Korean Society of Occupational and Environmental Hygiene)
- 제3권1호
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- Pages.37-53
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- 1993
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- 2384-132X(pISSN)
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- 2289-0564(eISSN)
코크스제조공정에서 탄화시간과 시료채취방법에 따른 다핵방향족탄화수소 발생에 관한 연구
A Study on Polynuclear Aromatic Hydrocarbons Emitted by Coking Time and Sampling Method in a Coke Oven Plant
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Yun, Chung Sik
(School of Public Health, Seoul National University) ;
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Paik, Nam Won
(School of Public Health, Seoul National University)
- 발행 : 1993.03.31
초록
The polynuclear hydrocarbons (PAHs) emitted from coke oven standpipe were sampled using three sampling systems, including glass fiber filter+silver membrane filter, glass fiber filter+silver membrane filter+XAD-2 adsorbent tube, PTFE membrane filter+XAD-2 adsorbent tube, extracted by methylene chloride and analysed by gas chromathography using flame ionization detector. The results of this study were as follows. 1. Because the amounts of coke oven emissions(COE) were large, the analyses of PAHs were simple and possible without evaporation and concentration. Although the generation of COE was high during early stage of coking, the airborne concentration of PAHs was low and increased during late coking. 2. The contents of PAHs in COE were 1.35-2.81%. 3. The index components of PAHs were fluoranthene and pyrene. Their correlation coefficient to total PAHs were 0.96, 0.95, respectively. 4. The particulate PAHs were sampled by filter and gaseous PAHs by adsorbent tube. The collection efficiency of glass fiber filter+silver membrane filter was 20% of total amount sampled by filters+adsorbent and PTFE membrane filter 50%. Adsorbent tube must be attached to the filter to collect light and small PAH components. 5. The generation of acenaphthene and indeno (1,2,3-cd) pyrene were low and concentrations of fluorene and anthracene were
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