Elastomers and Composites
- Volume 28 Issue 4
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- Pages.267-273
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- 1993
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- 2092-9676(pISSN)
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- 2288-7725(eISSN)
The Effect of Various Hydrophilic Acrylic Comonomers on Soap-Free Emulsion Polymerization of Styrene-Butadiene Rubber
Styrene-Butadiene 무유화제 유화공중합에서의 아크릴계 친수성 공단량체의 영향
- Chung, Huey-Sil (Research and Development Center, Hyundai Petrochemical Co., Ltd.) ;
- Lee, Chang-Sung (Department of Polymer Science and Engineering, Pusan National University) ;
- Kim, Byung-Kyu (Department of Polymer Science and Engineering, Pusan National University) ;
- Shin, Young-Jo (Department of Polymer Science and Engineering, Pusan National University)
- Published : 1993.12.31
Abstract
A number of hydrophilic acrylic comonomers were incorporated into styrene-butadiene soap-free emulsion polymerization. It was found that reaction rate decreased according to : AN>AA>MMA>EA>IA>AAM>MA>HEMA. It was also observed that reaction rate increased with decreasing H-bonding factor contribution to the solubility parameter of the hydrophilic comonoer. The SBR latexes were very monodisperse with the particle size distribution of
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