대한화학회지 (Journal of the Korean Chemical Society)

  • 제37권8호
  • /
  • Pages.717-722
  • /
  • 1993
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

황함유 리간드의 금속착물(II). 디티오카바메이트류의 백금(II) 착물의 합성과 성질

Metal Complexes of Sulfur-Containing Ligands (II). Synthesis and Properties of Platinum(II) Complexes of Dithiocarbamates

  • 김찬우 (大邱大學校 師範大學 化學敎育科) ;
  • 김창수 (大邱大學校 師範大學 化學敎育科)
  • Chan-Woo Kim (Department of Chemical Education, Taegu University) ;
  • Chang-Su Kim (Department of Chemical Education, Taegu University)
  • 발행 : 1993.08.20
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초록

물에서 [PtCl$_4$]^{2-}$의 백금(II)에 결합된 클로로리간드를 디티오카바메이트로 치환시켜 [Pt(A)], [Pt(B)$_2$]Cl$_2$, [Pt(C)$_2$] 및 [Pt(D)(CH$_2$=CH$_2$)Cl]Cl를 합성하였다. 백금 착물은 원소분석, 적외선 및 자외선-가시광선 스펙트럼과 전도도 측정을 하여 이들의 성질을 조사하였따. 이들 백금(II)의 디티오카바메이트류 착물은 물, 알코올, 디메틸술폭시드 및 티메틸포름아미드와 같은 극성용매에 잘 녹았다. 이들 백금(II) 착물의 원소분석과 물리적 측정결과에서부터 그 가능한 구조를 제시하였다.

Reactions of [PtCl$_4$]$^{2-}$ with excess of dithiocarbamates in water lead to facile replacement of the chloro ligand by dithiocarbamato ligand to give [Pt(A)], [Pt(B)$_2$]Cl$_2$, [Pt(C)$_2$], and [Pt(D)(CH$_2$=CH$_2$)Cl]Cl. The complexes of platinum have been characterized by elemental analyses, infrared and UV-visible spectra, and conductivity measurements. Platinum(II)-dithiocarbamate complexes were soluble in polar solvents such as water, alcohol, acetone, dimethylformamide, and dimethylsulfoxide etc. The possible structure was proposed on the basis of elemental analyses and physical properties.

키워드

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