Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Generation and Reactivities of Silaethene $Cl_2Si=CHCH_{2}^{t}Bu$-Unsaturated Compounds of 14 group Elements (Ⅸ)

실라에텐 $Cl_2Si=CHCH_{2}^{t}Bu$의 생성과 반응성

  • Chung-Kyun Kim (Department of Chemistry, Dong-A University) ;
  • Eunmi Park (Department of Chemistry, Dong-A University) ;
  • Mi-Young Ku (Department of Chemistry, Dong-A University) ;
  • Kyungglae Park (College of Pharmacy, Chumgnam National University) ;
  • Byung-Yun Son (Department of Pharmacy, Chumgnam National University)
  • 김정균 (동아대학교 자연과학대학 화학과) ;
  • 박은미 (동아대학교 자연과학대학 화학과) ;
  • 구미영 (동아대학교 자연과학대학 화학과) ;
  • 박경래 (충남대학교 약학대학) ;
  • 손병영 (단국대학교 문리과대학 화학과)
  • Published : 1993.02.20
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Abstract

Silaethene $Cl_2$Si=$CHCH_2^tBu$, generated as a metastable reaction intermediate by the thermal eliminatio of LiCl from lithiated compound $Cl_2$Si=$CHCH_2^tBu$, react with propene, 2-methylpropene, 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, and anthracene to give ene-reaction product, 2+2-, and 2+4-cycloadducts. They are isolated by vacuum fractional distillation method and spectroscopically identified.

Lithiated 화합물인 $Cl_3$Si=$CHCH_2^tBu$로부터 LiCl의 제거반응에 의해 생성된 준안정 반응중간체인 Silaethene, $Cl_2$Si=$CHCH_2^tBu$은 propene, 2-methylpropene, 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, anthracene과 반응하여 엔반응 생성물, 2 + 2-, 2 + 4- 고리화부가생성물을 생성한다. 이들을 분별진공증류법에 의해 분리하였고 분광학적으로 확인하였다.

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References

  1. 대학원논문집 동아대학교
  2. J. Organomet. Chem. v.273 N. Wiberg
  3. Dokl. Akad. Nauk SSSR v.171 N. S. Nametkin;L. E. Gusel'nikov;V. M. Vdovin;P. L. Grinberg;V. I. Zavlyalov;V. D. Opengaim
  4. Chem. Abstr. v.66 N. S. Nametkin;L. E. Gusel'nikov;V. M. Vdovin;P. L. Grinberg;V. I. Zavlyalov;V. D. Opengaim
  5. Chem. Rev. v.79 L. E. Gusel'nikov;N. S. Nametkin
  6. Chem. Rev. v.85 G. Raabe;J. Michl
  7. Chem. Ber. v.114 N. Wiberg;C. Preiner;O. Schieda;G. Fischer
  8. Chem. Ber. v.114 N. Wiberg;G. Preiner;O. Schieda
  9. Chem. Ber. v.114 N. Wiberg;G. Preiner;O. Schieda
  10. Allg. Chem. v.558 N. Auner;Z. Anorg
  11. Allg. Chem. v.558 N. Auner;Z. Anorg
  12. J. Organomet. Chem. v.353 N. Auner
  13. J. Organomet. Chem. v.377 N. Auner
  14. J. Organomet. Chem. v.366 N. Auner
  15. Angew. Chem. Int. Ed, Engl. v.30 N. Auner;C. Seidenschwarz;E. Hertweck;N. Sewald
  16. Angew. Chem. Int. Ed, Engl. v.30 N. Auner;C. Seidenschwarz;E. Hertweck;N. Sewald
  17. J. Am. Chem. Soc. v.102 P. R. Jones;T. F. A. Lim;R. A. Pierce
  18. Organometallics v.3 P. R. Jones;A. H. B. Cheng;T. E. Albanesi
  19. Organometallics v.2 P. R. Jones;R. A. Pierce;A. H. B. Cheng
  20. Angew. Int. Ed, Engl. v.22 N. Wiberg;G. Wagner
  21. Chem. Ber. v.119 N. Wiberg;Ch.-K. Kim
  22. Chem. Ber. v.119 N. Wiberg;Ch.-K. Kim
  23. Dissertation. Univ. Munchen Ch.-K. Kim
  24. Dissertation. Univ. Munchen H. Kopf
  25. Dissertation. Univ. Muchen P. Karampatses
  26. Angew. Chem. v.81 H. M. R. Hoffmann
  27. Justus Liebigs Ann. Chem. v.460 O. Diels;K. Alder
  28. Angew. Chem. v.79 J. Sauer
  29. Angew. Chem. v.92 J. Sauer;R. Sustman
  30. J. Am. Chem. Soc. v.99 P. R. Jones;T. F. O. Lim