Bulletin of the Korean Chemical Society

  • 제14권6호
  • /
  • Pages.749-752
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  • 1993
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Selective Reduction of $\alpha,\beta$-Unsaturated Ketones with Borohydride Exchange Resin-$CuSO_4$ in Methanol

  • 발행 : 1993.12.20
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초록

Borohydride exchange resin $(BER)-CuSO_4$ system readily reduces {\alpha},{\beta}$-unsaturated ketones to the corresponding saturated alcohols quantitatively. This reduction tolerates many functional groups such as carbon-carbon multiple bonds, chlorides, epoxides, esters, amides and nitriles.

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참고문헌

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피인용 문헌

  1. Reducing Characteristics of Borohydride Exchange Resin–CuSO4 in Methanol vol.70, pp.5, 1997, https://doi.org/10.1246/bcsj.70.1101
  2. A fast procedure for the preparation of vicinal azidoalcohols using polymer supported reagents vol.46, pp.27, 1993, https://doi.org/10.1016/j.tetlet.2005.05.023
  3. Superparamagnetic Core‐Shell‐Type Fe3O4/Ru Nanoparticles as Catalysts for the Selective Hydrogenation of an Unconstrained α,β‐Unsaturated Ketone vol.2012, pp.4, 1993, https://doi.org/10.1002/ejic.201100869