Bulletin of the Korean Chemical Society

  • 제14권6호
  • /
  • Pages.722-726
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  • 1993
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Di- and Triorganotin(IV) Complexes of Sulfur-containing Ylidenemalonates

  • Jung, Ok-Sang (Inorganic Chemistry Laboratory, Korea Institute of Scinece & Technology) ;
  • Lee, Young-A (Inorganic Chemistry Laboratory, Korea Institute of Scinece & Technology) ;
  • Hong, Jong-Ki (Advanced Analysis Center, Korea Institute of Science & Technology) ;
  • Jeong, Jong-Hwa (Department of Chemistry, Kyungpook National Uiversity) ;
  • Sohn, Youn-Soo (Inorganic Chemistry Laboratory, Korea Institute of Scinece & Technology)
  • 발행 : 1993.12.20
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초록

Organotin(IV) complexes of ylidenemalonates $(R_xSn)_{x-1}(O_2C)_2C=C(SR')_2\;(R=n-C_4H_9,\;C_6H_5,\;cyclo-C_6H_{11},\;CH_3OOCCH_2CH_2;\;x=2,3;\;R'=CH_3,\;R_2'=-CHCH-,\;-CH_2CH_{2^-})$ have been synthesized and characterized by means of various spectroscopic methods. The X-ray crystal structure of $(Ph_3Sn)_2(O_2C)_2C=C(SCH_3)_2$ has been determined (Pi; a= 9.704(2) ${\AA}$, b= 14.412(1) ${\AA}$, c= 14.760(3) ${\AA}$, ${alpha}$=74.26(1)$^{\circ}$, ${beta}$=99.38(l)$^{\circ}$, ${\gamma}$=79.09(1)$^{\circ}$, $V= 1950.7(7){\AA}^3$) and refined to R= 0.045. The crystal structure discloses a discrete molecule with bidentate-like carboxylate ligand. For diorganotin analogues, the structures are discussed in terms of IR, $^1H-NMR,\;^{13}C-NMR$, and FAB mass spectrometry. The mass spectrum indicates that the diorganotin complexes of ylidenemalonates are dimeric.

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참고문헌

  1. Comprehensive Organometallic Chemistry v.2 A. G. Davis;P. J. Smith;G. Wilkinson(ed.);F. G. A. Stone(ed.);E. W. Abel(ed.)
  2. J. Organomet. Chem. Lib. 16 v.16 Organotin Compounds in Modern Technology C. J. Evans;S. Karpel
  3. Organometallic Compounds in the Environment Organotin Compounds in the Environment S. J. Blunden;A. Chapman;P. J. Craig(ed.)
  4. J. Organomet. Chem. Lib. 21 v.21 Organotin Chemistry I. Omae
  5. Metal-Based Anti-Tumor Drugs The Antitumor Activity of Tin Compounds A. J. Crowe;M. F. Gielen(ed.)
  6. Appl. Organomet. Chem. v.5 E. R. T. Tiekink
  7. Acc. Chem. Res. v.22 R. R. Holmes
  8. Inorg. Chem. v.26 V. Chandrasekhar;C. G. Schmid;S. D. Burton;J. M. Holmes;R. O. Day;R. R. Holmes
  9. Advances in Chemistry Series v.157 Organotin Compounds: New Chemistry and Applications R. E. Hutton;V. Oakes;J. J. Zuckerman(ed.)
  10. Acta Chem. Scand. v.17 E. Soderback
  11. Chem. Pharm. Bull. v.38 N. Katagiri;S. Ise;N. Watanabe;C. Kaneto
  12. International Tables for X-ray Crystallography v.IV
  13. SHELX 76: Program for Crystal Structure Determination G. M. Sheldrick
  14. J. Organomet. Chem. v.267 K. C. Molloy;T. G. Purcell;K. Quill;I. W. Nowell
  15. J. Organomet. Chem. v.191 S. Calogero;P. Ganis;V. Peruzo;G. Tagliavini
  16. Inorg. Chem. v.23 J. F. Vollano;R. O. Day;D. N. Rau;V. Chandrasekhar;R. R. Holmes
  17. J. Chem. Soc. A. N. W. Alcock;R. E. Timms
  18. Organometallics v.5 K. C. Molloy;T. G. Purcell;E. Hahn;H. Schumann;J. J. Zuckerman
  19. Inorg. Chem. v.25 R. R. Holmes;R. O. Day;V. Chandrasekhar;J. F. Vollano;R. R. Holmes
  20. Inorg. Chem. v.23 R. G. Swisher;J. F. Vollano;V. Chandrasekhar;R. O. Day;R. R. Holmes
  21. Appl. Organomet. Chem. v.1 K. C. Molloy;T. G. Purcell;M. F. Mahon;E. Minshall
  22. Acta Crystallogr. C. v.45 S. W. Ng;V. G. Kumar Das;F. Van Meurs;J. D. Schagen;L. H. Straver
  23. J. Chem. Soc., Dalton Trans. P. G. Harrison;K. Lambert;T. J. King;B. Majee
  24. O. S. Jung;Y. S. Sohn