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Photo-Crosslinking of Poly(glycidyl methacrylate) Initiated by N-Hydroxyphthalimide Sulfonates

  • Kyu Ho Chae (Department of Polymer Engineering, Chonnam National University) ;
  • Ik Ju Park (Department of Polymer Engineering, Chonnam National University) ;
  • Min Ho Choi (Department of Polymer Engineering, Chonnam National University)
  • Published : 1993.10.20

Abstract

The photoacid generation efficiency of four N-hydroxyphthalimide sulfonate derivatives was studied by photo-crosslinking reaction of poly(glycidyl methacrylate) in solid film state. The relative photoacid generation efficiency was increased in the order of N-hydroxyphthalimide methanesulfonate > -toluenesulfonate > -nitrobenzenesulfonate > -dinitrobenzensulfonate, and the reaction was efficiently sensitized by benzophenone suggesting that this photoreactions is likely to proceed through its triplet excited state.

Keywords

References

  1. J. Rad. Curing v.14 G. L. Bassi
  2. Chem. & Eng. News v.29 R. Seltzer
  3. Polymer Bulletin v.19 D. J. Wilson;A. D. Jenkins
  4. ACS Symposium Series 242 Polymers in Electronics J. V. Crivello;T. Davidso(ed.)
  5. J. Electrochem. Soc. v.133 C. G. Wilson;H. Ito;J. M. J. Frechet
  6. J. Polymer Sci. Symposium v.56 J. V. Crivello;J. H. W. Lam
  7. Macromolecules v.10 J. V. Crivello;J. H. W. Lam
  8. Chemtech v.10 J. V. Crivello
  9. Development in Polymer Photochemistry v.2 J. V. Crivello;N. S. Allen(ed.)
  10. J. Rad. Curing v.13 G. Berner;R. Kirchmayr;G. Rist;W. Rutsch
  11. Macromol. Chem. Rapid Commun. v.5 M. Shirai;T. Masuda;M. Tsunooka;M. Tanaka
  12. Macromolecules v.21 F. M. Houlihan;A. Shugard;R. Gooden;E. Reichmanis

Cited by

  1. Photoacid and photobase generators: Chemistry and applications to polymeric materials vol.21, pp.1, 1993, https://doi.org/10.1016/0079-6700(95)00014-3
  2. Development of 1‐Hydroxy‐2(1H)‐quinolone‐Based Photoacid Generators and Photoresponsive Polymer Surfaces vol.18, pp.38, 1993, https://doi.org/10.1002/chem.201104065