Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Cr(Ⅲ) Complexes of Tetraazamacrocycles Derived from $\alpha$-Diketones and Diaminoalkanes

  • Rai, Pramod K. (Department of Chemistry. University of Rajastan) ;
  • Gupta, Ajay K. (Department of Chemistry. University of Rajastan) ;
  • Prasad, Raghu N. (Department of Chemistry. University of Rajastan)
  • Published : 1993.04.20
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Abstract

Template condensation of ${\alpha}$-diketones such as 2,3-butanedione or benzil with diaminoalkanes such as 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, 1,8-diaminooctane or 1,12-diaminododecane in the presence of Cr(III) results in the formation of complexes of the type $[CrI,X_2]X$ (where L = tetraazamacrocycle having 12 to 32-membered ring and $X={NO_3}^- or Cl^-).$ The complexes have been characterized by elemental analyses, magnetic measurements and IR and diffuse reflectance spectra.

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References

  1. J. Am. Chem. Soc. v.95 D. A. Baldwin;P. M. Pfeiffer;D. W. Reichgott;N. J. Rose
  2. Inorg. Chem. v.11 S. C. Jackels;K. Farmery;E. K. Barefield;N. J. Rose;D. H. Busch
  3. 157th National Meeting of the Am. Chem. Soc. Minneapolis, Minn., No. INOR 20 D. A. Baldwin;N. J. Rose
  4. Inorg. Chem. v.23 M. J. Maroney;N. J. Rose
  5. Inorg. Chem. v.16 W. A. Welsh;G. J. Reynolds;P. M. Henry
  6. Inorg. Nucl. Chem. v.43 Y. K. Bhoon;R. P. Singh
  7. Inorg. Chem. v.20 R. G. Swisher;G. A. Brown;R. C. Smierciak;E. L. Blinn
  8. Inorg. Chem. v.24 N. A. P. K. Maguire;K. C. Wallace;D. B. Miller
  9. Inorg. Chem. v.25 N. A. P. K. Maguire;K. C. Wallace;D. P. Cobranchi;J. M. Derrick;D.G. Speece
  10. J. Prakt. Chem. v.333 R. N. Prasad;A. K. Gupta;P. K. Rai
  11. Annali Chim. Soc. Chim. Ital. v.81 R. N. Prasad;A. K. Gupta;P. K. Rai
  12. Monats. Chem. v.340 R. N. Prasad;D. S. Parihar
  13. Inorg. Chem. v.5 J. P. Collman;P. W. Schneider
  14. Inorg. Chem. v.12 V. L. Goedken;J. Molin-Case;G. G. Cristoph
  15. J. Am. Chem. Soc. v.87 J. L. Hoard;M. J. Hamor;T. A. Hamer;W. S. Gaughey
  16. J. Am. Chem. Soc. v.96 L. Y. Martin;L. J. Dehayes;L. J. Zompa;D. H. Busch
  17. Inorg. Chem. v.29 R. D. Hancock;M. P. Ngwenya;A. Evers;P. W. Wade;J. C. A. Boeyens;S. M. Dobson
  18. J. Chem. Soc. Dalton Trans. V. J. Thom;R. D. Hancock
  19. J. Chem. Soc. Dalton Trans. R. D. Hancock;M. P. Ngwenya
  20. J. Am. Chem. Soc. v.106 V. J. Thom;C. C. Fox;J. C. A. Boeyens;R. D. Hancock
  21. Inorg. Chem. v.19 D. S. Eggleston;S. C. Jackels
  22. J. Chem. Soc.Dalton Trans. M. G. B. Drew;A. H. bin Othman;S. G. Mcfall;P. D. A. Mcllroy;S. M. Nelson
  23. Inorg. Chem. v.22 S. C. Jackels;J. Ciavola;R. C. Carter;P. L. Cheek;T. D. Pascarelli
  24. J. Chem. Soc. Dalton Trans. N. W. Alcock;E. H. Curson;N. Herron;P. Moore
  25. Polyhedron v.1 V. B. Rana;P. Singh;D. P. Singh;M. P. Teotia
  26. Infrared Spectra of Inorganic and Coordination Compounds K. Nakamoto
  27. Inorg. Chim. Acta. v.5 C. K. Poon
  28. Inorg. Chem. v.29 P. V. Bernhardt;P. Comba;N. F. Curtis;T. W. Hambley;G. A. Lawrance;M. Maeder;A. Siriwardena