DOI QR코드

DOI QR Code

Spectroscopic Properties of cis-(1,4,8,11-Tetraazacyclotetradecane)(1,2-propanediamine)chromium(Ⅲ) Perchlorate$^1$

  • Jong-Ha Choi (Department of Chemistry, Andong National University)
  • 발행 : 1993.02.20

초록

The 77 K luminescence and excitation spectra, room-temperature FT-infrared and visible absorption spectra of a newly prepared complex cis-[Cr(cyclam)(pn)]$(ClO_4)_3$, where cyclam and pn represent 1,4,8,11-tetraazacyclotetradecane and 1,2-propanediamine respectively, have been measured. Absorption maximum of the first spin-allowed transition in the electronic absorption spectra of cis-[Cr(cyclam)(pn)]$^{3+}$ and cis-[Cr(cyclam)(en)]$^{3+}$ appears at nearly the same position. The two spin-allowed and six spin-forbidden electronic transitions are assigned from the visible absorption and excitation spectra. It is also shown that the zero phonon line in the excitation spectrum splits into two components by 50 cm$^{-1}$.

키워드

참고문헌

  1. Electronic Structure and Chemical Reactivity of Transition Metal Complexes
  2. Polyhedron v.11 J.-H. Choi;P. E. Hoggard
  3. Inorg. Chim. Acta v.4 J. Ferguson;M. L. Tobe
  4. J. Chem. Soc. Dalton Trans. M. E. Sosa;M. L. Tobe
  5. Ph.D. Thesis, The Ohio State University C. R. Sperati
  6. Inorg. Chem. v.9 E. Campi;J. Ferguson;M. L. Tobe
  7. Inorg. Chim. Acta v.72 D. A. House;O. Nor
  8. Inorg. chem. v.23 D. A. House;V. McKee
  9. Acta Cryst v.C42 E. Forsellini;T. Parasassi;G. Bombieri;M. L. Tobe;M. E. Sosa
  10. Inorg. Chem. v.30 A. D. Kirk;D. Heyd
  11. Inorg. Chem. v.30 D. A. Friesen;S.-H. Lee;J. Lilie;W. L. Waltz;L. Vincze
  12. Chem. Rev. v.90 L. S. Forster
  13. Ph.D. Thesis, Wayne State University R. B. Lessard
  14. Inorg. Chem. v.19 C.-K. Poon;K.-C. Pun
  15. J. Phys. Chem. v.85 K. Kuhn;F. Wasgestian;H. Kupka
  16. J. Chem. Soc. Faraday Trans., II v.68 C. D. Flint;P. Greenough
  17. J. Chem. Soc. Faraday Trans., II v.72 C. D. Flint;A. P. Matthews
  18. Inorg. Chem. v.24 N. A. P. Kane-Maguire;K. C. Wallace;D. B. Miller
  19. Inorganic Electronic Spectroscopy A. B. P. Lever
  20. Ph.D. Thesis, Kyungpook National University J.-H. Choi
  21. J. Phys. Soc. Jpn. v.9 Y. Tanabe;S. Sugano
  22. J. Inorg. Nucl. Chem. v.39 M. H. Sonar;A. S. R. Murty
  23. Inorg. Chem. v.17 C. F. C. Wong;A. D. Kirk
  24. J. Inorg. Nucl. Chem. v.27 J. H. Dunlop;R. D. Gillard
  25. J. Inorg. Nucl. Chem. v.27 Erratum
  26. Inorg. Chem. v.27 A. D. Kirk;A. M. Ibrahim
  27. Inorg. Chem. v.29 P. V. Bernhardt;P. Comba;N. F. Curtis;T. W. Hambley;G. A. Lawrance;M. Maeder;A. Siriwardena
  28. Polyhedron v.11 J.-H. Choi;P. E. Hoggard
  29. Spectrochim. Acta v.16 A. Sabatini;S. Califano
  30. Infrared and Raman Spectra of Inorganic and Coordination Compounds K. Nakamoto
  31. Spectrochim. Acta v.22 I. Nakagawa;T. Shimanouchi
  32. Inorg. Chim. Acta v.5 C.-K. Poon
  33. Inorg. Chim. Acta v.2 H. H. Schmidtke;D. Garthoff
  34. Transition Met. Chem. v.16 K.-W. Lee;P. E. Hoggard
  35. Coord. Chem. Rev. v.70 P. E. Hoggard

피인용 문헌

  1. trans-[CrX2([15]aneN4)]+(X=F,CI)의 전자분광학과 리간드장 해석 vol.47, pp.2, 1993, https://doi.org/10.5012/jkcs.2003.47.2.109
  2. Electronic and Vibrational Spectroscopy of cis-Diisothiocyanato(1,4,8,11-tetraazacyclotetradecane)chromium(Ⅲ) Thiocyanate vol.24, pp.3, 1993, https://doi.org/10.5012/bkcs.2003.24.3.384
  3. Crystal structure and spectroscopic properties of oxalato(1,4,8,11-tetraazacyclotetradecane)chromium(III) perchlorate vol.694, pp.1, 1993, https://doi.org/10.1016/j.molstruc.2004.01.034
  4. Spectroscopic Properties and Ligand Field Analysis of trans -Dibromo(2,2-dimethyl-1,3-diaminopropane)chromium(III) Moiety vol.26, pp.6, 1993, https://doi.org/10.5012/bkcs.2005.26.6.903
  5. Crystal Structure and IR Spectroscopy of cis-[Cr(cyclam)(ONO)2]NO2 vol.49, pp.2, 2005, https://doi.org/10.5012/jkcs.2005.49.2.239
  6. Crystal Structure and Spectroscopic Properties of cisβ-[CrCl_2(1,4,8,11-tetrazaundecane)chromium(III) Perchlorate vol.29, pp.7, 1993, https://doi.org/10.5012/bkcs.2008.29.7.1399
  7. Crystal Structure and Spectroscopic Properties of trans-Dibromobis(1,2-ethanediamine)chromium(III) Perchlorate vol.40, pp.7, 1993, https://doi.org/10.1007/s10870-010-9698-6
  8. Synthesis, Spectroscopic and Ligand Field Properties of trans-Difluorobis(2,2-dimethylpropane-1,3-diamine)chromium(III) Perchlorate vol.32, pp.1, 1993, https://doi.org/10.5012/bkcs.2011.32.1.296