황산-탄소섬유 층간화합물에서 얻은 잔류화합물의 특성

Properties of Residue Compounds Obtained from H2SO4-Carbon Fiber Intercalated Compound

  • 김인기 (한양대학교 무기재료공학과) ;
  • 최상흘 (한양대학교 무기재료공학과) ;
  • 고영신 (서울교육대학교 부설 탄소화학연구소)
  • 발행 : 1993.12.01

초록

The residue compounds of sulfuric acid-carbon fiber system were obtained from P100, M40, TZ307, and T300 fibers. The fibers which easily formed intercalation compound had small change of d002 value, but, large change of diameter of fiber. It was considered that the cracks in carbon fiber were due to the this conflicting result. The resistivities of residue compound of carbon fibers were increased with the large change of diameter of fibers. It is thought that the reason of our results is increasing defects such as crack in fibers. From the UV reflection spectra, it was found that reflectances of residue compounds were all decreased and the residue compounds were more stable than intercalation compounds.

키워드

참고문헌

  1. An Interpretive Review Synth. Met. v.5 Graphite Intercalation Chemistry W.C. Forsman;T. Dziemianowicz;K. Leong;Carl
  2. Synth. Met. v.23 Stability of Graphite Fibers Intercalation with Metal Chlorides A. Ansart C. Meschi;S. Falndrois
  3. Carbon v.16 The Intercalation of Graphitized Carbon Fibers and It's Removal J.G. Hooley
  4. Synth. Met. v.23 Stabilities of Metal-Halides Intercalation Graphite T. Sugiura;T. Hjima;M. Sato;K. Fujimoto
  5. Interstitial Compounds of Graphite Progress in Organic Chemistry v.1 G.R. Hennig;F. Albert Cotton(ed.)
  6. v.30 no.9 The Properties of The Interstitial Compounds of Graphite. III. The Electrical Properties of The Halogen Compounds of Graphite G.R. Hennig
  7. Adv. Inorg. Chem. Radiochem. v.23 Graphite Intercalation Compound Henry Selig;L.B. Ebert
  8. 요업학회지 v.30 no.10 탄소섬유의 구조가 섬유층간 화합물의 구조에 미치는 영향 김인기;최상흘;고영신
  9. Extended Abstracts of the 21th Biennial Conference on Cerbon A Study on the Observation of Deintercalation of Hydrogensulfate in Graphite Won-Chun Oh;Sung-June Cho;Jong-Ho Lee;Young-Shin Ko
  10. Mat. Sci. Eng. v.38 Synthesis and Properties of Lithium-Graphite Intercalation Compounds S. Basu;C. Zeller;P.J. Flanders;C.D. Fuerst;W.D. Johnson;J.E. Fischer
  11. Mater. Scie. Eng. v.31 Electronic properties of Graphite Intercalation Compound J.E. Fischer