Synthesis Polyurethane Coating Materials Containing Polysiloxane

Polysiloxane을 함유하는 Polyurethane Coating 재료의 합성

  • Yoo, Young-Mi (Department of Chemistry, Chungbuk National University) ;
  • Kim, Kong-Soo (Department of Industrial Chemical Engineering, Chungbuk National University) ;
  • Chun, Yong-Chul (Department of Industrial Chemical Engineering, Chungbuk National University) ;
  • Kang, Seog-Ho (Department of Industrial Chemical Engineering, Chungbuk National University) ;
  • Shin, Jae-Sup (Department of Chemistry, Chungbuk National University)
  • Published : 1992.12.31

Abstract

Polydimethylsiloxane(PDMS)-containing polyurethane coating materials were synthesized because PDMS-based elastomers have unique properties including an extremely low glass transition temperature, good thermal and oxidative stability, and good dielectric properties. In this experiment a vinyl copolymer which consisted of vinyl chloride, vinyl acetate, vinyl alcohol, and maleic acid was used, and Coronate L was used as a polyisocyanate. PDMS-containing polyurethane was synthesized from polydimethylsiloxane, MDI, and 1,4-butanediol. Films were casted by reaction of viny copolymer, Coronate L, and PDMS-containing polyurethane. Thickness of tile films were $150-170{\mu}m$ and the films were characterized by IR, DSC, and Instron.

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