DOI QR코드

DOI QR Code

Photochemistry of Conjugated Polyacethylenes: Photoaddition Reactions of 1-Phenyl-1,3,5-hexatriynes to Tetrahydrofuran

  • Shim, Sang Chul (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Lee, Cheon Seok (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Lee, Seong Taek (Department of Chemistry, The Korea Advanced Institute of Science and Technology)
  • 발행 : 1992.12.20

초록

Photolysis of 1-phenyl-1,3,5-hexatriynes in deaerated tetrahydrofuran gave photoreduction and photoaddition products, while photolysis of 1-phenyl-1,3,5-hexatriynes in deaerated alcoholic solvents (methanol, i-propanol) yielded dark red products, probably oligomers or decomposition products of reactants, as exclusive major products. A plausible mechanism for the reaction is proposed.

키워드

참고문헌

  1. J. Org. Chem. v.38 G. Ahlgren
  2. J. Org. Chem. v.37 P. Singh
  3. J. Org. Chem. v.34 G. Buchi;S. H. Feairheller
  4. J. Am. Chem. Soc. v.103 Y. Inoue;Y. Ueda;T. Hakushi
  5. Tetrahedron Lett. v.8 D. A. Ben-Efraim
  6. J. Photochem. Photobiol., A: Chemistry v.53 S. C. Shim;T. S. Lee
  7. Biochem. Syst. Ecol. v.14 D. McLachlan;T. Arnason;J. Lam
  8. Photochem. Photobiol. v.42 D. Weir;J. C. Scaiano;T. Arnason;C. Evans
  9. Photochem. Photobiol. v.43 J. B. Hudson;E. A. Graham;G. H. N. Towers
  10. Photochem. Photobiol. v.36 J. B. Hudson;E. A. Graham;G. H. N. Towers
  11. Photochem. Photobiol. v.39 D. McLachlan;T. Arnason;J. Lam
  12. Photochem. Photobiol. v.39 J. Kagan;K. T. Wielandt;G. Chan;S. N. Shawan;J. Jaworsky;I. Prakash;S. K. Arora
  13. Photochem. Photobiol. v.55 S. C. Shim;C. S. Lee
  14. Chem. Phys. Lett. v.11 D. Demoulin
  15. J .Org. Chem. v.32 V. I. Stenberg;R. D. Olson;C. T. Wang;N. Kulevsky
  16. J. Org. Chem. v.35 V. I. Stenberg;C. T. Wang;N. Kulevsky
  17. J. Org. Chem. v.38 G. Ahlgren
  18. Bull. Korean Chem. Soc. v.7 S. C. Shim;T. S. Lee
  19. Purification of Laboratory Chemicals D. D. Perrin;W. L. F. Armarego;B. R. Perrin