Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Michaelis-Menten Behaviour in the Oxidation of Benzaldehydes by Pyridinium Chlorochromate (Corey's Reagent)

  • Ganesh P. Panigrahi (Department of Chemistry, Berhampur University) ;
  • Sasananda Padhy (Department of Chemistry, Berhampur University)
  • Published : 1992.10.20
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Abstract

The oxidation of benzaldehyde, 3,4-dimethoxy benzaldehyde, p-methoxy benzaldehyde, m-$NO_2$-benzaldehyde, and m-chlorobenzaldehyde by pyridinium chlorochromate (Corey's reagent) are reported. Michaelis-Menten behaviour is observed. The rate determining step appears to be the decomposition of a complex of benzaldehyde with PCC either through a loss of $H^+$ or $H^-$ ions.

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References

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