DOI QR코드

DOI QR Code

Synthesis of Tetradecker Sandwich Complex with 1,4-Dialkyl-1,4-dibora-2,5-cyclohexadiene

  • Published : 1992.10.20

Abstract

A tetradecker sandwich compiex (7a) was synthesized in low yield by the reaction of a tripledecker, bis(${\eta}^5$-cyclopentadienyl)-${\mu}$-(${\eta}^6$-1,2,3,4-tetramethyl 1,4-dibora-2,5-cyclohexadiene) dinickel (5a) with potassium and Fe$Cl_2$${\cdot}$2THF. The reaction of another tripledecker, bis(${\eta}^5$-cyclopentadienyl)-${\mu}$-(${\eta}^6$-2,3-diethyl-1,4-dimethyl-1,4-dibora-2,5-cyclohex adiene) dicobalt (4a) with potassium and Fe$Cl_2$${\cdot}$2THF at room temperature produced a doubledecker complex (2b) via the decomposition of the dark green crystal.

Keywords

References

  1. J. Am. Chem. Soc. v.100 R. N. Camp;D. S. Marynick;G. D. Graham;W. N. Lipscomb
  2. J. Organomet. Chem. v.192 C. E. Herberich;B. He${\beta}$ner;s. Beswetherick;J. A. K. Howard;P. Woodward
  3. J. Kor. Chem. Soc. v.34 J. K. Uhm;D. Hu;U. Zenneck;H. Pritzkow;W. Siebert
  4. Angew. Chem. v.94 W. Siebert;J. Edwin;H. Wadepohl;H. Pritzkow
  5. Ph. D. Dissertation, Universitaet Marburg H. Wadepohl
  6. Organometallics v.2 J. Edwin;M. C. Boehm;N. Chester;D. M. Hoffmann;R. Hoffmann;H. Pritzkow;W. Siebert;K. Stumpt;H. Wadepohl
  7. Angew. Chem. v.92 K. Jonas;C. Krueger
  8. Angew. Chem. Int. Ed. Engl. v.22 K. Jonas
  9. Ph. D. Dissertation, Universitaet Heidelberg J. K. Uhm
  10. Chem. Ber. v.91 E. O. Fischer;C. Palm
  11. J. Chem. Soc. J. F. Tilney-Basset
  12. Chem. Ber. v.123 K. F. Woerner;J. K. Uhm;H. Pritzkow;W. Siebert
  13. Angew. Chem. v.89 W. Siebert;W. Rothermel
  14. Angew. Chem. v.91 W. Siebert;W. Rothermel;C. Boehle;C. Krueger;D. J. Brauer
  15. Ph. D. Dissertation, Universitaet Heidelberg D. Buechner

Cited by

  1. 1.4-Dibora-2,5-cyclohexadiene 유도체를 리간드로 갖는 니켈 Double-decker 착물의 합성 vol.46, pp.3, 1992, https://doi.org/10.5012/jkcs.2002.46.3.213
  2. 상자성 코발트 트리플-덱카, Bis-(η5-cyclopentadienyl)-μ-(η6-2,3-diethyl-1,4,5,6-tetramethyl-1,4-dibora-2,5-cyclohexadiene) Dicobalt의 확인 vol.47, pp.3, 2003, https://doi.org/10.5012/jkcs.2003.47.3.292